Acta Cryst. (2007). E63, m2545  [ doi:10.1107/S160053680704439X ]

(p-Methylbenzenethiolato)[tris(3-phenyl-5-methylpyrazolyl)borato]zinc(II)

H. Görls, W. Günther, J. Notni and E. Anders

Abstract: The crystal structure of the title compound, [Zn(C₃₀H₂₈BN₆)(C₇H₇S)], is closely related to a series of other tripod zinc thiolates. The Zn atom adopts a very distorted tetrahedral coordination geometry. In addition to the crystallographic data, ¹¹B NMR as well as ¹¹B-decoupled ¹H NMR data are provided. A proton shift for the boron-bound hydride (5.15 p.p.m.) of a pyrazolylborato ligand is reported for the first time.

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