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Acta Cryst. (2007). E63, m2617 [ doi:10.1107/S1600536807046430 ]
2O:O')dicopper(II)(Cu-Cu) bis(methanol-
O)tetrakis(2,3,5-triiodobenzoato-
2O:O')dicopper(II)(Cu-Cu) methanol disolvateAbstract: The title cocrystal, [Cu2(C7H2I3O2)4(H2O)2][Cu2(C7H2I3O2)4(CH4O)2]·2CH4O, contains two dinuclear complexes. In both centrosymmetric molecules, four triiodobenzoates bridge a pair of Cu atoms. The Cu atoms show square-pyramidal coordination; for one, the apical position is occupied by a water molecule, and for the other, this site is occupied by a methanol molecule.
Online 29 September 2007
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