Acta Cryst. (2007). E63, m2529-m2530 [ doi:10.1107/S1600536807043929 ]
Abstract: In the title complex, (C21H22P)[Au(C3S5)2] or (Ph3C3H7P)[Au(dmit)2] (where Ph3C3H7P is the triphenyl-n-propylphosphonium cation and dmit is the 2-thioxo-1,3-dithiole-4,5-dithiolate anion), the AuIII atom exhibits a square-planar coordination involving four S atoms from two dmit ligands. The [Au(dmit)2]- anions form discrete pairs with a long intermolecular AuS interaction for each Au atom in the crystal structure.
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