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Acta Cryst. (2007). E63, m2596    [ doi:10.1107/S1600536807045321 ]

Di-[mu]-nitrosyl-bis[([eta]5-pentamethylcyclopentadienyl)ruthenium(0)](Ru-Ru)

M. Pearsal, M. Gembicky, P. Dominiak, A. Larsen and P. Coppens

Abstract top

The title structure, [Ru2(C10H15)2(NO)2], consists of the two Ru atoms doubly bridged via the N atoms of the two NO groups, with two pentamethylcyclopentadienyl (Cp*) rings protruding away from the bridged system on opposite sides. The asymmetric unit contains two independent dimer molecules with an average Ru-Ru distance of 2.538 (7) Å and an average Ru-N-Ru angle of 97.2 (3)°. The compound was obtained as the product of a facile reaction between Cp*Ru(NO)(OSO2CF3)2 and excess neat 2-propanol. The crystals were grown from CH2Cl2 solution at ambient temperature under a nitrogen atmosphere.

Comment top

X-ray diffraction data on title compound were collected at 90 (1) K using a Bruker SMART APEX2 CCD diffractometer installed at a rotating anode source (Mo Kα radiation, λ =0.71073 Å), and equipped with an Oxford Cryosystems nitrogen gas-flow apparatus. The data were collected by the oscillation method with 0.5°frame-width (ω-scan) and a 15 sec exposure per frame. Four sets of data (360 frames in each set) were collected, nominally covering complete reciprocal space. The data were integrated, scaled, sorted and averaged using the APEX2 software package.

All crystals examined were twinned. The metric symmetry of the unit cell suggested a monoclinic C-centred cell. However the structure could be solved, with some difficulties, in the triclinic space group P 1 only (Direct Methods, SHELXTL Version 6.14). The twin law (0 - 1 0, -1 0 0, 0 0 - 1) was used during refinement. The volume ratios of the twins refined to 0.298 (1): 0.702 (1).

All non-hydrogen atoms were refined anisotropically. Positions of hydrogen atoms were calculated from the geometry of surrounding carbon atoms. The CH3 H atoms were treated as part of idealized CH3 groups with Uiso=1.5Ueq. For the carbon atoms C22, C31 and C35 isotropic restraints have been imposed to avoid non positive definite ADPs.

Related literature top

For related literature, see: Bergman & Chang (1987); Bernal et al. (1977); Bottomley (1983); Burns & Hubbard (1994); Hayton et al. (2002); Kubat-Martin et al. (1987).

Experimental top

All synthetic procedures were carried out in the inert atmosphere of a glove box. The starting material - Cp*Ru(NO)OTf2 (OTf = OSO2CF3) – was prepared according to synthetic methods reported by Burns & Hubbard (1994). 2-Propanol (10 ml) was added with a syringe to Cp*Ru(NO)OTf2 (125 mg, 0.22 mmol) with a syringe. A color change from green to red/brown was observed immediately upon addition of 2-propanol to Cp*Ru(NO)OTf2. This color persisted throughout the reaction. The solution was stirred for ~2 h after which the deep red microcrystalline powder was collected by filtration. The product was washed with diethyl ether and dried, yielding 37 mg (.068 mmol, 62% yield). The structure was confirmed by 1H NMR and 13C NMR spectroscopy. Alternate routes entailing reductive elimination of Cp*Ru(NO)Cl2 or Cp*Ru(NO)Ph2 have been reported by Bergman & Chang (1987) and Hayton et al. (2002) Recrystallization was attempted in several solvents. The highest quality crystals (and ultimately, the crystal used for x-ray analysis) were obtained from CH2Cl2 solutions.

Refinement top

Support of the REU program CHE-0453206 by the national Science Foundation is gratefully acknowledged.

Computing details top

Data collection: APEX2 (Bruker, 2004); cell refinement: APEX2 (Bruker, 2004); data reduction: SAINT (Bruker, 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2000); software used to prepare material for publication: SHELXTL (Sheldrick, 2000).

Figures top
[Figure 1] Fig. 1. Molecular structure of title compound, hydrogen atoms are omitted for clarity. Displacement ellipsoids are drawn at the 50% probability level.
Di-µ-nitrosyl-bis[(η5-pentamethylcyclopentadienyl)ruthenium(0)](Ru—Ru) top
Crystal data top
[Ru2(C10H15)2(NO)2]Z = 4
Mr = 532.60F(000) = 1072
Triclinic, P1Dx = 1.721 Mg m−3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.7181 (3) ÅCell parameters from 7139 reflections
b = 10.7364 (3) Åθ = 3–28°
c = 17.9238 (5) ŵ = 1.49 mm−1
α = 89.209 (1)°T = 90 K
β = 89.220 (1)°Parallelepiped, red
γ = 85.373 (1)°0.3 × 0.2 × 0.13 mm
V = 2055.48 (10) Å3
Data collection top
Bruker SMART APEXII
diffractometer		10102 independent reflections
Radiation source: rotating anode9591 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.040
Detector resolution: 8.33 pixels mm-1θmax = 28.3°, θmin = 1.9°
ω scansh = −14→14
Absorption correction: multi-scan
(SADABS; Bruker 2004)		k = −14→14
Tmin = 0.705, Tmax = 0.824l = −23→23
29941 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.046Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.139H-atom parameters constrained
S = 1.26 w = 1/[σ2(Fo2) + (0.0465P)2 + 11.2766P]
where P = (Fo2 + 2Fc2)/3
10102 reflections(Δ/σ)max = 0.001
490 parametersΔρmax = 2.12 e Å−3
18 restraintsΔρmin = −2.33 e Å−3
Crystal data top
[Ru2(C10H15)2(NO)2]γ = 85.373 (1)°
Mr = 532.60V = 2055.48 (10) Å3
Triclinic, P1Z = 4
a = 10.7181 (3) ÅMo Kα radiation
b = 10.7364 (3) ŵ = 1.49 mm−1
c = 17.9238 (5) ÅT = 90 K
α = 89.209 (1)°0.3 × 0.2 × 0.13 mm
β = 89.220 (1)°
Data collection top
Bruker SMART APEXII
diffractometer		10102 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker 2004)		9591 reflections with I > 2σ(I)
Tmin = 0.705, Tmax = 0.824Rint = 0.040
29941 measured reflectionsθmax = 28.3°
Refinement top
R[F2 > 2σ(F2)] = 0.046 w = 1/[σ2(Fo2) + (0.0465P)2 + 11.2766P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.139Δρmax = 2.12 e Å−3
S = 1.26Δρmin = −2.33 e Å−3
10102 reflectionsAbsolute structure: ?
490 parametersFlack parameter: ?
18 restraintsRogers parameter: ?
H-atom parameters constrained
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ru10.83429 (5)0.25167 (5)0.55223 (3)0.01071 (12)
Ru20.69033 (5)0.26716 (5)0.44039 (3)0.01077 (12)
Ru30.74543 (5)0.83347 (5)1.05050 (3)0.01092 (12)
Ru40.75823 (6)0.69028 (6)0.93893 (3)0.01274 (13)
N10.8686 (5)0.2772 (5)0.4483 (3)0.0138 (10)
N20.6564 (5)0.2350 (5)0.5441 (3)0.0120 (10)
N30.7691 (5)0.8663 (5)0.9461 (3)0.0137 (10)
N40.7283 (6)0.6576 (6)1.0431 (3)0.0165 (11)
O10.9603 (5)0.2868 (5)0.4067 (3)0.0186 (10)
O20.5687 (5)0.2106 (5)0.5845 (3)0.0178 (10)
O30.7819 (5)0.9550 (5)0.9043 (3)0.0188 (10)
O40.7083 (6)0.5701 (5)1.0848 (3)0.0248 (11)
C11.0123 (6)0.3019 (6)0.6016 (3)0.0153 (12)
C20.9088 (6)0.3454 (6)0.6490 (3)0.0133 (12)
C30.8506 (6)0.2399 (7)0.6759 (3)0.0157 (13)
C40.9122 (7)0.1307 (6)0.6430 (3)0.0157 (13)
C51.0147 (6)0.1707 (7)0.5976 (3)0.0196 (14)
C61.1027 (7)0.3803 (7)0.5625 (4)0.0229 (14)
H6A1.18610.36280.58390.034*
H6B1.07530.46890.56880.034*
H6C1.10600.36060.50930.034*
C70.8771 (8)0.4764 (7)0.6728 (4)0.0242 (15)
H7A0.78710.48910.68360.036*
H7B0.89940.53390.63270.036*
H7C0.92400.49260.71770.036*
C80.7401 (7)0.2394 (7)0.7287 (4)0.0229 (14)
H8A0.75930.17900.76920.034*
H8B0.66690.21590.70170.034*
H8C0.72230.32290.74950.034*
C90.8799 (8)−0.0006 (7)0.6564 (4)0.0271 (16)
H9A0.7887−0.00330.65640.041*
H9B0.9125−0.03050.70480.041*
H9C0.9172−0.05420.61690.041*
C101.1114 (7)0.0898 (7)0.5546 (4)0.0245 (15)
H10A1.12340.12660.50500.037*
H10B1.08280.00590.54960.037*
H10C1.19080.08430.58140.037*
C110.6615 (6)0.3406 (6)0.3248 (3)0.0133 (12)
C120.5575 (6)0.3859 (7)0.3712 (3)0.0165 (13)
C130.4952 (6)0.2823 (7)0.3977 (3)0.0193 (14)
C140.5631 (6)0.1703 (7)0.3703 (4)0.0177 (13)
C150.6642 (7)0.2080 (6)0.3252 (3)0.0176 (13)
C160.7511 (7)0.4163 (7)0.2847 (4)0.0208 (13)
H16A0.83680.38390.29620.031*
H16B0.73790.50350.30040.031*
H16C0.73790.41180.23080.031*
C170.5142 (7)0.5198 (7)0.3828 (4)0.0240 (15)
H17A0.45920.54930.34190.036*
H17B0.58670.56970.38370.036*
H17C0.46810.52830.43030.036*
C180.3795 (7)0.2856 (8)0.4461 (4)0.0272 (16)
H18A0.35600.37170.46120.041*
H18B0.39600.23300.49050.041*
H18C0.31100.25410.41800.041*
C190.5247 (7)0.0418 (7)0.3822 (4)0.0238 (14)
H19A0.48500.03550.43150.036*
H19B0.5986−0.01800.37930.036*
H19C0.46520.02310.34370.036*
C200.7578 (7)0.1247 (7)0.2829 (4)0.0227 (14)
H20A0.74450.13700.22920.034*
H20B0.74770.03740.29650.034*
H20C0.84250.14520.29510.034*
C210.6700 (6)1.0141 (6)1.0968 (3)0.0140 (12)
C220.6316 (6)0.9149 (7)1.1443 (3)0.0164 (13)
C230.7421 (7)0.8505 (7)1.1744 (3)0.0167 (13)
C240.8494 (7)0.9067 (7)1.1437 (3)0.0179 (13)
C250.8036 (6)1.0098 (6)1.0966 (3)0.0134 (12)
C260.5862 (7)1.1095 (7)1.0562 (4)0.0230 (15)
H26A0.58331.18911.08260.035*
H26B0.50171.08121.05410.035*
H26C0.61871.12091.00540.035*
C270.5004 (7)0.8876 (7)1.1648 (4)0.0250 (15)
H27A0.47840.92211.21400.038*
H27B0.49440.79701.16610.038*
H27C0.44250.92601.12760.038*
C280.7445 (8)0.7443 (7)1.2286 (4)0.0246 (15)
H28A0.82990.72611.24700.037*
H28B0.71730.67031.20400.037*
H28C0.68800.76641.27070.037*
C290.9852 (7)0.8728 (7)1.1631 (4)0.0227 (14)
H29A1.00220.90581.21230.034*
H29B1.03950.90891.12560.034*
H29C1.00170.78161.16390.034*
C300.8801 (6)1.0991 (7)1.0552 (4)0.0196 (13)
H30A0.96921.07361.06160.029*
H30B0.86141.18331.07490.029*
H30C0.85981.09891.00210.029*
C310.7173 (7)0.6749 (7)0.8191 (4)0.0205 (15)
C320.6613 (8)0.5753 (9)0.8593 (5)0.033 (2)
C330.7600 (9)0.4985 (8)0.8929 (4)0.0311 (19)
C340.8759 (7)0.5494 (7)0.8756 (4)0.0207 (14)
C350.8486 (6)0.6582 (6)0.8296 (3)0.0141 (12)
C360.6512 (9)0.7775 (10)0.7736 (4)0.042 (3)
H36A0.67660.85840.78980.064*
H36B0.56060.77530.78040.064*
H36C0.67330.76590.72070.064*
C370.5250 (11)0.5529 (14)0.8582 (7)0.073 (5)
H37A0.50990.49580.81770.110*
H37B0.47510.63240.85020.110*
H37C0.50080.51570.90600.110*
C380.7469 (14)0.3831 (9)0.9393 (5)0.066 (4)
H38A0.81070.37710.97820.100*
H38B0.75800.30940.90750.100*
H38C0.66350.38730.96260.100*
C391.0063 (9)0.4968 (9)0.8946 (4)0.040 (2)
H39A1.00230.43670.93610.060*
H39B1.05630.56480.90910.060*
H39C1.04510.45450.85100.060*
C400.9426 (7)0.7408 (7)0.7966 (4)0.0248 (15)
H40A0.94670.73070.74230.037*
H40B1.02510.71740.81780.037*
H40C0.91720.82820.80820.037*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0143 (3)0.0127 (2)0.0044 (2)0.00371 (17)−0.00232 (18)−0.00081 (18)
Ru20.0137 (2)0.0132 (2)0.0047 (2)0.00386 (17)−0.00250 (18)−0.00123 (18)
Ru30.0137 (2)0.0128 (3)0.0058 (2)0.00216 (17)−0.00055 (18)−0.00242 (19)
Ru40.0167 (3)0.0142 (3)0.0073 (2)−0.00047 (19)0.00158 (19)−0.0039 (2)
N10.017 (3)0.016 (3)0.008 (2)0.0050 (19)−0.002 (2)0.000 (2)
N20.013 (3)0.012 (3)0.011 (2)0.0018 (18)−0.0028 (19)−0.0030 (19)
N30.015 (3)0.014 (3)0.011 (2)0.002 (2)−0.002 (2)−0.004 (2)
N40.018 (3)0.018 (3)0.014 (3)−0.004 (2)0.002 (2)−0.003 (2)
O10.021 (2)0.024 (3)0.011 (2)−0.0013 (19)0.0020 (18)−0.0005 (19)
O20.017 (2)0.024 (3)0.011 (2)0.0000 (18)0.0014 (18)0.0019 (19)
O30.034 (3)0.013 (2)0.009 (2)0.0006 (19)−0.0011 (19)0.0024 (17)
O40.041 (3)0.019 (3)0.016 (2)−0.008 (2)0.008 (2)0.001 (2)
C10.017 (3)0.021 (3)0.008 (3)0.000 (2)−0.005 (2)−0.005 (2)
C20.017 (3)0.015 (3)0.007 (3)0.002 (2)−0.001 (2)−0.003 (2)
C30.016 (3)0.027 (4)0.004 (3)0.000 (3)0.000 (2)0.002 (2)
C40.024 (3)0.014 (3)0.010 (3)−0.002 (2)−0.010 (2)0.002 (2)
C50.019 (3)0.029 (4)0.009 (3)0.012 (3)−0.005 (2)−0.002 (3)
C60.023 (3)0.033 (4)0.012 (3)0.001 (3)0.001 (2)−0.006 (3)
C70.037 (4)0.023 (3)0.012 (3)0.005 (3)0.001 (3)−0.010 (3)
C80.025 (4)0.034 (4)0.009 (3)−0.002 (3)0.002 (3)0.003 (3)
C90.045 (5)0.020 (3)0.016 (3)−0.004 (3)−0.008 (3)0.005 (3)
C100.027 (4)0.027 (4)0.018 (3)0.013 (3)−0.004 (3)−0.007 (3)
C110.017 (3)0.017 (3)0.005 (2)0.003 (2)−0.001 (2)0.000 (2)
C120.017 (3)0.023 (3)0.008 (3)0.009 (2)−0.004 (2)−0.001 (2)
C130.016 (3)0.034 (4)0.008 (3)0.004 (3)−0.004 (2)0.001 (3)
C140.019 (3)0.025 (3)0.009 (3)−0.001 (2)−0.007 (2)0.001 (2)
C150.026 (3)0.019 (3)0.007 (3)0.007 (3)−0.007 (2)−0.007 (2)
C160.027 (3)0.024 (3)0.011 (3)0.000 (3)−0.001 (2)0.004 (3)
C170.027 (4)0.023 (3)0.020 (3)0.011 (3)−0.006 (3)−0.004 (3)
C180.022 (4)0.044 (5)0.015 (3)0.000 (3)−0.002 (3)0.001 (3)
C190.031 (4)0.022 (3)0.020 (3)−0.009 (3)−0.004 (3)0.004 (3)
C200.030 (4)0.026 (3)0.010 (3)0.008 (3)−0.001 (3)−0.006 (3)
C210.016 (3)0.016 (3)0.010 (3)0.003 (2)−0.001 (2)−0.006 (2)
C220.019 (3)0.024 (3)0.006 (3)0.003 (2)0.004 (2)−0.008 (2)
C230.025 (3)0.018 (3)0.007 (3)0.000 (3)0.000 (2)−0.007 (2)
C240.028 (4)0.018 (3)0.008 (3)0.003 (3)−0.005 (2)−0.003 (2)
C250.019 (3)0.015 (3)0.006 (2)0.001 (2)0.000 (2)−0.002 (2)
C260.020 (3)0.024 (4)0.023 (3)0.010 (3)−0.005 (3)−0.003 (3)
C270.023 (3)0.034 (4)0.018 (3)−0.003 (3)0.009 (3)−0.006 (3)
C280.041 (4)0.021 (4)0.012 (3)−0.002 (3)−0.002 (3)−0.002 (3)
C290.022 (3)0.026 (4)0.019 (3)0.006 (3)−0.006 (3)−0.001 (3)
C300.025 (3)0.018 (3)0.016 (3)−0.003 (2)0.000 (2)−0.001 (2)
C310.025 (3)0.026 (4)0.010 (3)0.004 (3)−0.004 (2)−0.013 (3)
C320.027 (4)0.047 (5)0.026 (4)−0.019 (4)0.012 (3)−0.026 (4)
C330.057 (6)0.021 (4)0.016 (3)−0.011 (3)0.016 (3)−0.010 (3)
C340.034 (4)0.020 (3)0.006 (3)0.011 (3)−0.003 (2)−0.007 (2)
C350.020 (3)0.017 (3)0.005 (2)0.002 (2)0.004 (2)−0.006 (2)
C360.045 (5)0.058 (6)0.019 (4)0.028 (4)−0.021 (3)−0.019 (4)
C370.053 (7)0.105 (11)0.069 (8)−0.040 (7)0.026 (6)−0.070 (8)
C380.153 (13)0.023 (5)0.026 (4)−0.028 (6)0.039 (6)−0.009 (4)
C390.057 (6)0.040 (5)0.018 (3)0.033 (4)−0.011 (3)−0.010 (3)
C400.035 (4)0.029 (4)0.011 (3)−0.008 (3)0.011 (3)−0.005 (3)
Geometric parameters (Å, º) top
Ru1—N11.915 (5)C14—C191.483 (10)
Ru1—N21.937 (5)C15—C201.495 (9)
Ru1—C42.199 (6)C16—H16A0.9800
Ru1—C22.208 (6)C16—H16B0.9800
Ru1—C52.215 (6)C16—H16C0.9800
Ru1—C12.223 (6)C17—H17A0.9800
Ru1—C32.227 (6)C17—H17B0.9800
Ru1—Ru22.5418 (7)C17—H17C0.9800
Ru2—N21.921 (5)C18—H18A0.9800
Ru2—N11.929 (6)C18—H18B0.9800
Ru2—C152.197 (6)C18—H18C0.9800
Ru2—C142.199 (6)C19—H19A0.9800
Ru2—C122.214 (6)C19—H19B0.9800
Ru2—C112.224 (6)C19—H19C0.9800
Ru2—C132.229 (7)C20—H20A0.9800
Ru3—N31.917 (5)C20—H20B0.9800
Ru3—N41.918 (6)C20—H20C0.9800
Ru3—C212.208 (6)C21—C251.429 (9)
Ru3—C242.208 (6)C21—C221.437 (10)
Ru3—C222.212 (6)C21—C261.494 (9)
Ru3—C252.214 (6)C22—C231.430 (10)
Ru3—C232.230 (6)C22—C271.500 (9)
Ru3—Ru42.5347 (7)C23—C241.441 (10)
Ru4—N31.908 (6)C23—C281.488 (10)
Ru4—N41.923 (6)C24—C251.442 (9)
Ru4—C352.194 (6)C24—C291.515 (9)
Ru4—C342.206 (7)C25—C301.493 (9)
Ru4—C312.210 (6)C26—H26A0.9800
Ru4—C322.222 (7)C26—H26B0.9800
Ru4—C332.227 (8)C26—H26C0.9800
N1—O11.235 (7)C27—H27A0.9800
N2—O21.222 (7)C27—H27B0.9800
N3—O31.219 (7)C27—H27C0.9800
N4—O41.224 (8)C28—H28A0.9800
C1—C51.409 (10)C28—H28B0.9800
C1—C21.440 (9)C28—H28C0.9800
C1—C61.495 (10)C29—H29A0.9800
C2—C31.412 (9)C29—H29B0.9800
C2—C71.486 (9)C29—H29C0.9800
C3—C41.428 (10)C30—H30A0.9800
C3—C81.506 (9)C30—H30B0.9800
C4—C51.447 (10)C30—H30C0.9800
C4—C91.495 (9)C31—C351.419 (9)
C5—C101.508 (9)C31—C321.447 (12)
C6—H6A0.9800C31—C361.498 (11)
C6—H6B0.9800C32—C331.423 (14)
C6—H6C0.9800C32—C371.500 (13)
C7—H7A0.9800C33—C341.425 (12)
C7—H7B0.9800C33—C381.498 (12)
C7—H7C0.9800C34—C351.435 (9)
C8—H8A0.9800C34—C391.506 (11)
C8—H8B0.9800C35—C401.505 (9)
C8—H8C0.9800C36—H36A0.9800
C9—H9A0.9800C36—H36B0.9800
C9—H9B0.9800C36—H36C0.9800
C9—H9C0.9800C37—H37A0.9800
C10—H10A0.9800C37—H37B0.9800
C10—H10B0.9800C37—H37C0.9800
C10—H10C0.9800C38—H38A0.9800
C11—C151.422 (9)C38—H38B0.9800
C11—C121.439 (9)C38—H38C0.9800
C11—C161.480 (9)C39—H39A0.9800
C12—C131.416 (10)C39—H39B0.9800
C12—C171.490 (9)C39—H39C0.9800
C13—C141.443 (10)C40—H40A0.9800
C13—C181.502 (10)C40—H40B0.9800
C14—C151.425 (10)C40—H40C0.9800
N1—Ru1—N297.3 (2)H10A—C10—H10C109.5
N1—Ru1—C4136.9 (3)H10B—C10—H10C109.5
N2—Ru1—C4110.0 (2)C15—C11—C12107.2 (6)
N1—Ru1—C2128.8 (2)C15—C11—C16125.7 (6)
N2—Ru1—C2120.6 (2)C12—C11—C16127.0 (6)
C4—Ru1—C263.1 (2)C15—C11—Ru270.2 (3)
N1—Ru1—C5104.3 (2)C12—C11—Ru270.7 (3)
N2—Ru1—C5146.3 (3)C16—C11—Ru2123.6 (4)
C4—Ru1—C538.3 (3)C13—C12—C11108.5 (6)
C2—Ru1—C562.9 (2)C13—C12—C17125.5 (6)
N1—Ru1—C1100.8 (2)C11—C12—C17125.7 (7)
N2—Ru1—C1158.4 (2)C13—C12—Ru272.0 (4)
C4—Ru1—C163.0 (2)C11—C12—Ru271.4 (3)
C2—Ru1—C137.9 (2)C17—C12—Ru2127.5 (5)
C5—Ru1—C137.0 (3)C12—C13—C14107.9 (6)
N1—Ru1—C3163.2 (2)C12—C13—C18127.0 (7)
N2—Ru1—C399.1 (2)C14—C13—C18125.1 (7)
C4—Ru1—C337.7 (2)C12—C13—Ru270.8 (4)
C2—Ru1—C337.1 (2)C14—C13—Ru269.8 (4)
C5—Ru1—C362.8 (2)C18—C13—Ru2124.6 (4)
C1—Ru1—C362.4 (2)C15—C14—C13107.3 (6)
N1—Ru1—Ru248.86 (17)C15—C14—C19127.6 (7)
N2—Ru1—Ru248.52 (16)C13—C14—C19124.9 (7)
C4—Ru1—Ru2145.59 (17)C15—C14—Ru271.0 (4)
C2—Ru1—Ru2147.60 (18)C13—C14—Ru272.1 (4)
C5—Ru1—Ru2146.00 (17)C19—C14—Ru2126.5 (5)
C1—Ru1—Ru2147.30 (17)C11—C15—C14109.0 (6)
C3—Ru1—Ru2147.23 (17)C11—C15—C20124.2 (7)
N2—Ru2—N197.4 (2)C14—C15—C20126.8 (7)
N2—Ru2—C15145.9 (3)C11—C15—Ru272.3 (3)
N1—Ru2—C15104.4 (2)C14—C15—Ru271.1 (4)
N2—Ru2—C14110.2 (2)C20—C15—Ru2123.8 (4)
N1—Ru2—C14137.1 (3)C11—C16—H16A109.5
C15—Ru2—C1437.8 (3)C11—C16—H16B109.5
N2—Ru2—C12121.4 (2)H16A—C16—H16B109.5
N1—Ru2—C12127.6 (3)C11—C16—H16C109.5
C15—Ru2—C1262.9 (2)H16A—C16—H16C109.5
C14—Ru2—C1263.2 (3)H16B—C16—H16C109.5
N2—Ru2—C11159.2 (2)C12—C17—H17A109.5
N1—Ru2—C1199.9 (2)C12—C17—H17B109.5
C15—Ru2—C1137.5 (2)H17A—C17—H17B109.5
C14—Ru2—C1163.2 (2)C12—C17—H17C109.5
C12—Ru2—C1137.8 (2)H17A—C17—H17C109.5
N2—Ru2—C1399.5 (2)H17B—C17—H17C109.5
N1—Ru2—C13162.6 (2)C13—C18—H18A109.5
C15—Ru2—C1362.9 (3)C13—C18—H18B109.5
C14—Ru2—C1338.0 (3)H18A—C18—H18B109.5
C12—Ru2—C1337.2 (3)C13—C18—H18C109.5
C11—Ru2—C1362.7 (2)H18A—C18—H18C109.5
N2—Ru2—Ru149.06 (16)H18B—C18—H18C109.5
N1—Ru2—Ru148.36 (15)C14—C19—H19A109.5
C15—Ru2—Ru1145.55 (17)C14—C19—H19B109.5
C14—Ru2—Ru1146.36 (18)H19A—C19—H19B109.5
C12—Ru2—Ru1147.44 (18)C14—C19—H19C109.5
C11—Ru2—Ru1145.97 (17)H19A—C19—H19C109.5
C13—Ru2—Ru1148.02 (17)H19B—C19—H19C109.5
N3—Ru3—N497.1 (2)C15—C20—H20A109.5
N3—Ru3—C21104.8 (2)C15—C20—H20B109.5
N4—Ru3—C21147.1 (2)H20A—C20—H20B109.5
N3—Ru3—C24127.1 (3)C15—C20—H20C109.5
N4—Ru3—C24120.4 (3)H20A—C20—H20C109.5
C21—Ru3—C2463.5 (2)H20B—C20—H20C109.5
N3—Ru3—C22137.8 (3)C25—C21—C22108.4 (6)
N4—Ru3—C22111.1 (3)C25—C21—C26124.9 (6)
C21—Ru3—C2237.9 (2)C22—C21—C26126.6 (6)
C24—Ru3—C2263.6 (3)C25—C21—Ru371.4 (4)
N3—Ru3—C2599.8 (2)C22—C21—Ru371.2 (4)
N4—Ru3—C25158.4 (2)C26—C21—Ru3125.0 (4)
C21—Ru3—C2537.7 (2)C23—C22—C21107.7 (6)
C24—Ru3—C2538.1 (2)C23—C22—C27124.8 (7)
C22—Ru3—C2563.4 (2)C21—C22—C27127.3 (6)
N3—Ru3—C23162.8 (3)C23—C22—Ru371.9 (4)
N4—Ru3—C2399.3 (3)C21—C22—Ru370.9 (3)
C21—Ru3—C2362.9 (2)C27—C22—Ru3126.3 (5)
C24—Ru3—C2337.9 (3)C22—C23—C24108.4 (6)
C22—Ru3—C2337.6 (2)C22—C23—C28125.4 (7)
C25—Ru3—C2363.0 (2)C24—C23—C28126.2 (6)
N3—Ru3—Ru448.36 (17)C22—C23—Ru370.6 (3)
N4—Ru3—Ru448.78 (17)C24—C23—Ru370.3 (4)
C21—Ru3—Ru4146.67 (16)C28—C23—Ru3125.4 (5)
C24—Ru3—Ru4145.42 (19)C23—C24—C25107.4 (6)
C22—Ru3—Ru4147.66 (18)C23—C24—C29126.6 (6)
C25—Ru3—Ru4145.37 (16)C25—C24—C29125.8 (7)
C23—Ru3—Ru4147.50 (18)C23—C24—Ru371.9 (4)
N3—Ru4—N497.2 (2)C25—C24—Ru371.2 (4)
N3—Ru4—C3599.6 (2)C29—C24—Ru3126.9 (5)
N4—Ru4—C35155.4 (3)C21—C25—C24108.0 (6)
N3—Ru4—C34130.1 (3)C21—C25—C30125.1 (6)
N4—Ru4—C34117.9 (3)C24—C25—C30126.9 (6)
C35—Ru4—C3438.1 (2)C21—C25—Ru370.9 (4)
N3—Ru4—C31100.5 (3)C24—C25—Ru370.8 (4)
N4—Ru4—C31153.2 (3)C30—C25—Ru3124.7 (4)
C35—Ru4—C3137.6 (2)C21—C26—H26A109.5
C34—Ru4—C3163.3 (2)C21—C26—H26B109.5
N3—Ru4—C32132.2 (3)H26A—C26—H26B109.5
N4—Ru4—C32116.2 (3)C21—C26—H26C109.5
C35—Ru4—C3263.2 (3)H26A—C26—H26C109.5
C34—Ru4—C3263.1 (3)H26B—C26—H26C109.5
C31—Ru4—C3238.1 (3)C22—C27—H27A109.5
N3—Ru4—C33161.7 (3)C22—C27—H27B109.5
N4—Ru4—C33101.0 (3)H27A—C27—H27B109.5
C35—Ru4—C3362.8 (3)C22—C27—H27C109.5
C34—Ru4—C3337.5 (3)H27A—C27—H27C109.5
C31—Ru4—C3362.9 (3)H27B—C27—H27C109.5
C32—Ru4—C3337.3 (4)C23—C28—H28A109.5
N3—Ru4—Ru348.64 (16)C23—C28—H28B109.5
N4—Ru4—Ru348.63 (18)H28A—C28—H28B109.5
C35—Ru4—Ru3143.66 (18)C23—C28—H28C109.5
C34—Ru4—Ru3145.77 (19)H28A—C28—H28C109.5
C31—Ru4—Ru3145.23 (19)H28B—C28—H28C109.5
C32—Ru4—Ru3148.8 (2)C24—C29—H29A109.5
C33—Ru4—Ru3149.5 (2)C24—C29—H29B109.5
O1—N1—Ru1138.4 (5)H29A—C29—H29B109.5
O1—N1—Ru2138.7 (4)C24—C29—H29C109.5
Ru1—N1—Ru282.8 (2)H29A—C29—H29C109.5
O2—N2—Ru2139.1 (4)H29B—C29—H29C109.5
O2—N2—Ru1138.4 (4)C25—C30—H30A109.5
Ru2—N2—Ru182.4 (2)C25—C30—H30B109.5
O3—N3—Ru4138.1 (4)H30A—C30—H30B109.5
O3—N3—Ru3138.9 (5)C25—C30—H30C109.5
Ru4—N3—Ru383.0 (2)H30A—C30—H30C109.5
O4—N4—Ru3137.9 (5)H30B—C30—H30C109.5
O4—N4—Ru4139.5 (5)C35—C31—C32107.7 (7)
Ru3—N4—Ru482.6 (2)C35—C31—C36125.2 (8)
C5—C1—C2108.3 (6)C32—C31—C36127.1 (8)
C5—C1—C6125.0 (6)C35—C31—Ru470.6 (3)
C2—C1—C6126.8 (6)C32—C31—Ru471.4 (4)
C5—C1—Ru171.2 (4)C36—C31—Ru4123.9 (5)
C2—C1—Ru170.5 (4)C33—C32—C31107.5 (7)
C6—C1—Ru1123.9 (4)C33—C32—C37127.4 (10)
C3—C2—C1107.9 (6)C31—C32—C37124.9 (10)
C3—C2—C7125.5 (6)C33—C32—Ru471.6 (4)
C1—C2—C7126.2 (6)C31—C32—Ru470.5 (4)
C3—C2—Ru172.2 (4)C37—C32—Ru4127.8 (6)
C1—C2—Ru171.6 (3)C32—C33—C34108.8 (7)
C7—C2—Ru1127.2 (5)C32—C33—C38126.6 (10)
C2—C3—C4108.5 (6)C34—C33—C38124.6 (10)
C2—C3—C8126.9 (6)C32—C33—Ru471.1 (4)
C4—C3—C8124.5 (6)C34—C33—Ru470.4 (4)
C2—C3—Ru170.7 (3)C38—C33—Ru4124.2 (5)
C4—C3—Ru170.1 (3)C33—C34—C35107.4 (7)
C8—C3—Ru1123.8 (4)C33—C34—C39128.4 (8)
C3—C4—C5107.3 (6)C35—C34—C39124.1 (8)
C3—C4—C9125.9 (7)C33—C34—Ru472.1 (4)
C5—C4—C9126.8 (7)C35—C34—Ru470.5 (4)
C3—C4—Ru172.2 (3)C39—C34—Ru4126.8 (5)
C5—C4—Ru171.5 (3)C31—C35—C34108.7 (6)
C9—C4—Ru1123.9 (4)C31—C35—C40125.2 (6)
C1—C5—C4107.9 (6)C34—C35—C40126.2 (7)
C1—C5—C10124.4 (7)C31—C35—Ru471.8 (4)
C4—C5—C10127.7 (7)C34—C35—Ru471.4 (4)
C1—C5—Ru171.8 (4)C40—C35—Ru4123.4 (4)
C4—C5—Ru170.2 (4)C31—C36—H36A109.5
C10—C5—Ru1125.0 (4)C31—C36—H36B109.5
C1—C6—H6A109.5H36A—C36—H36B109.5
C1—C6—H6B109.5C31—C36—H36C109.5
H6A—C6—H6B109.5H36A—C36—H36C109.5
C1—C6—H6C109.5H36B—C36—H36C109.5
H6A—C6—H6C109.5C32—C37—H37A109.5
H6B—C6—H6C109.5C32—C37—H37B109.5
C2—C7—H7A109.5H37A—C37—H37B109.5
C2—C7—H7B109.5C32—C37—H37C109.5
H7A—C7—H7B109.5H37A—C37—H37C109.5
C2—C7—H7C109.5H37B—C37—H37C109.5
H7A—C7—H7C109.5C33—C38—H38A109.5
H7B—C7—H7C109.5C33—C38—H38B109.5
C3—C8—H8A109.5H38A—C38—H38B109.5
C3—C8—H8B109.5C33—C38—H38C109.5
H8A—C8—H8B109.5H38A—C38—H38C109.5
C3—C8—H8C109.5H38B—C38—H38C109.5
H8A—C8—H8C109.5C34—C39—H39A109.5
H8B—C8—H8C109.5C34—C39—H39B109.5
C4—C9—H9A109.5H39A—C39—H39B109.5
C4—C9—H9B109.5C34—C39—H39C109.5
H9A—C9—H9B109.5H39A—C39—H39C109.5
C4—C9—H9C109.5H39B—C39—H39C109.5
H9A—C9—H9C109.5C35—C40—H40A109.5
H9B—C9—H9C109.5C35—C40—H40B109.5
C5—C10—H10A109.5H40A—C40—H40B109.5
C5—C10—H10B109.5C35—C40—H40C109.5
H10A—C10—H10B109.5H40A—C40—H40C109.5
C5—C10—H10C109.5H40B—C40—H40C109.5
N1—Ru1—Ru2—N2177.2 (3)C14—Ru2—C12—C11−80.1 (4)
C4—Ru1—Ru2—N261.1 (4)C13—Ru2—C12—C11−117.5 (6)
C2—Ru1—Ru2—N2−82.7 (4)Ru1—Ru2—C12—C11119.6 (4)
C5—Ru1—Ru2—N2132.4 (4)N2—Ru2—C12—C1760.4 (7)
C1—Ru1—Ru2—N2−157.1 (4)N1—Ru2—C12—C17−71.0 (7)
C3—Ru1—Ru2—N2−10.2 (4)C15—Ru2—C12—C17−158.6 (7)
N2—Ru1—Ru2—N1−177.2 (3)C14—Ru2—C12—C17158.8 (7)
C4—Ru1—Ru2—N1−116.1 (4)C11—Ru2—C12—C17−121.2 (8)
C2—Ru1—Ru2—N1100.1 (4)C13—Ru2—C12—C17121.4 (8)
C5—Ru1—Ru2—N1−44.8 (4)Ru1—Ru2—C12—C17−1.6 (9)
C1—Ru1—Ru2—N125.8 (4)C11—C12—C13—C142.2 (7)
C3—Ru1—Ru2—N1172.6 (4)C17—C12—C13—C14176.1 (6)
N1—Ru1—Ru2—C1544.9 (4)Ru2—C12—C13—C14−60.3 (4)
N2—Ru1—Ru2—C15−132.3 (4)C11—C12—C13—C18−178.1 (6)
C4—Ru1—Ru2—C15−71.2 (5)C17—C12—C13—C18−4.2 (11)
C2—Ru1—Ru2—C15145.0 (5)Ru2—C12—C13—C18119.4 (7)
C5—Ru1—Ru2—C150.1 (5)C11—C12—C13—Ru262.5 (4)
C1—Ru1—Ru2—C1570.6 (5)C17—C12—C13—Ru2−123.6 (6)
C3—Ru1—Ru2—C15−142.5 (5)N2—Ru2—C13—C12130.8 (4)
N1—Ru1—Ru2—C14115.7 (4)N1—Ru2—C13—C12−34.3 (10)
N2—Ru1—Ru2—C14−61.5 (4)C15—Ru2—C13—C12−80.1 (4)
C4—Ru1—Ru2—C14−0.5 (5)C14—Ru2—C13—C12−118.3 (5)
C2—Ru1—Ru2—C14−144.3 (5)C11—Ru2—C13—C12−37.8 (4)
C5—Ru1—Ru2—C1470.9 (5)Ru1—Ru2—C13—C12121.4 (4)
C1—Ru1—Ru2—C14141.4 (5)N2—Ru2—C13—C14−110.8 (4)
C3—Ru1—Ru2—C14−71.8 (5)N1—Ru2—C13—C1484.0 (10)
N1—Ru1—Ru2—C12−97.2 (4)C15—Ru2—C13—C1438.2 (4)
N2—Ru1—Ru2—C1285.6 (4)C12—Ru2—C13—C14118.3 (5)
C4—Ru1—Ru2—C12146.7 (5)C11—Ru2—C13—C1480.6 (4)
C2—Ru1—Ru2—C122.9 (5)Ru1—Ru2—C13—C14−120.2 (4)
C5—Ru1—Ru2—C12−142.0 (5)N2—Ru2—C13—C188.5 (7)
C1—Ru1—Ru2—C12−71.5 (5)N1—Ru2—C13—C18−156.6 (7)
C3—Ru1—Ru2—C1275.4 (5)C15—Ru2—C13—C18157.6 (8)
N1—Ru1—Ru2—C11−24.8 (4)C14—Ru2—C13—C18119.4 (8)
N2—Ru1—Ru2—C11158.0 (4)C12—Ru2—C13—C18−122.3 (8)
C4—Ru1—Ru2—C11−140.9 (5)C11—Ru2—C13—C18−160.1 (8)
C2—Ru1—Ru2—C1175.3 (4)Ru1—Ru2—C13—C18−0.8 (9)
C5—Ru1—Ru2—C11−69.6 (5)C12—C13—C14—C15−1.8 (7)
C1—Ru1—Ru2—C110.9 (4)C18—C13—C14—C15178.5 (6)
C3—Ru1—Ru2—C11147.8 (5)Ru2—C13—C14—C15−62.7 (4)
N1—Ru1—Ru2—C13−170.5 (4)C12—C13—C14—C19−176.7 (6)
N2—Ru1—Ru2—C1312.3 (4)C18—C13—C14—C193.6 (10)
C4—Ru1—Ru2—C1373.4 (5)Ru2—C13—C14—C19122.4 (6)
C2—Ru1—Ru2—C13−70.4 (5)C12—C13—C14—Ru260.9 (4)
C5—Ru1—Ru2—C13144.7 (5)C18—C13—C14—Ru2−118.8 (6)
C1—Ru1—Ru2—C13−144.8 (5)N2—Ru2—C14—C15−164.5 (4)
C3—Ru1—Ru2—C132.1 (5)N1—Ru2—C14—C15−37.8 (5)
N4—Ru3—Ru4—N3177.4 (3)C12—Ru2—C14—C1579.6 (4)
C21—Ru3—Ru4—N343.1 (4)C11—Ru2—C14—C1537.0 (4)
C24—Ru3—Ru4—N3−97.6 (4)C13—Ru2—C14—C15116.2 (6)
C22—Ru3—Ru4—N3116.7 (4)Ru1—Ru2—C14—C15−119.5 (4)
C25—Ru3—Ru4—N3−27.6 (4)N2—Ru2—C14—C1379.3 (4)
C23—Ru3—Ru4—N3−169.5 (4)N1—Ru2—C14—C13−154.0 (4)
N3—Ru3—Ru4—N4−177.4 (3)C15—Ru2—C14—C13−116.2 (6)
C21—Ru3—Ru4—N4−134.3 (4)C12—Ru2—C14—C13−36.6 (4)
C24—Ru3—Ru4—N485.0 (4)C11—Ru2—C14—C13−79.2 (4)
C22—Ru3—Ru4—N4−60.6 (4)Ru1—Ru2—C14—C13124.3 (4)
C25—Ru3—Ru4—N4155.1 (4)N2—Ru2—C14—C19−41.4 (7)
C23—Ru3—Ru4—N413.2 (4)N1—Ru2—C14—C1985.4 (7)
N3—Ru3—Ru4—C3534.7 (4)C15—Ru2—C14—C19123.2 (8)
N4—Ru3—Ru4—C35−147.9 (4)C12—Ru2—C14—C19−157.2 (7)
C21—Ru3—Ru4—C3577.8 (4)C11—Ru2—C14—C19160.2 (7)
C24—Ru3—Ru4—C35−62.9 (4)C13—Ru2—C14—C19−120.6 (8)
C22—Ru3—Ru4—C35151.4 (5)Ru1—Ru2—C14—C193.7 (9)
C25—Ru3—Ru4—C357.1 (4)C12—C11—C15—C140.7 (7)
C23—Ru3—Ru4—C35−134.8 (5)C16—C11—C15—C14179.8 (6)
N3—Ru3—Ru4—C34103.4 (4)Ru2—C11—C15—C1462.0 (4)
N4—Ru3—Ru4—C34−79.3 (4)C12—C11—C15—C20179.3 (6)
C21—Ru3—Ru4—C34146.4 (5)C16—C11—C15—C20−1.6 (10)
C24—Ru3—Ru4—C345.8 (5)Ru2—C11—C15—C20−119.3 (6)
C22—Ru3—Ru4—C34−139.9 (5)C12—C11—C15—Ru2−61.4 (4)
C25—Ru3—Ru4—C3475.8 (5)C16—C11—C15—Ru2117.7 (6)
C23—Ru3—Ru4—C34−66.1 (5)C13—C14—C15—C110.7 (7)
N3—Ru3—Ru4—C31−32.5 (4)C19—C14—C15—C11175.4 (6)
N4—Ru3—Ru4—C31144.8 (4)Ru2—C14—C15—C11−62.8 (4)
C21—Ru3—Ru4—C3110.5 (5)C13—C14—C15—C20−177.9 (6)
C24—Ru3—Ru4—C31−130.1 (5)C19—C14—C15—C20−3.2 (11)
C22—Ru3—Ru4—C3184.2 (5)Ru2—C14—C15—C20118.7 (6)
C25—Ru3—Ru4—C31−60.1 (5)C13—C14—C15—Ru263.5 (4)
C23—Ru3—Ru4—C31158.0 (5)C19—C14—C15—Ru2−121.9 (7)
N3—Ru3—Ru4—C32−105.9 (6)N2—Ru2—C15—C11144.6 (4)
N4—Ru3—Ru4—C3271.4 (6)N1—Ru2—C15—C11−87.5 (4)
C21—Ru3—Ru4—C32−62.9 (6)C14—Ru2—C15—C11118.0 (6)
C24—Ru3—Ru4—C32156.5 (6)C12—Ru2—C15—C1137.7 (4)
C22—Ru3—Ru4—C3210.8 (6)C13—Ru2—C15—C1179.7 (4)
C25—Ru3—Ru4—C32−133.5 (6)Ru1—Ru2—C15—C11−120.5 (4)
C23—Ru3—Ru4—C3284.6 (6)N2—Ru2—C15—C1426.5 (6)
N3—Ru3—Ru4—C33176.9 (6)N1—Ru2—C15—C14154.5 (4)
N4—Ru3—Ru4—C33−5.7 (6)C12—Ru2—C15—C14−80.3 (4)
C21—Ru3—Ru4—C33−140.0 (6)C11—Ru2—C15—C14−118.0 (6)
C24—Ru3—Ru4—C3379.3 (6)C13—Ru2—C15—C14−38.4 (4)
C22—Ru3—Ru4—C33−66.4 (6)Ru1—Ru2—C15—C14121.5 (4)
C25—Ru3—Ru4—C33149.4 (6)N2—Ru2—C15—C20−95.7 (7)
C23—Ru3—Ru4—C337.4 (6)N1—Ru2—C15—C2032.3 (7)
N2—Ru1—N1—O1−173.6 (7)C14—Ru2—C15—C20−122.2 (8)
C4—Ru1—N1—O1−43.7 (9)C12—Ru2—C15—C20157.5 (7)
C2—Ru1—N1—O146.8 (8)C11—Ru2—C15—C20119.8 (8)
C5—Ru1—N1—O1−19.8 (8)C13—Ru2—C15—C20−160.6 (7)
C1—Ru1—N1—O118.1 (8)Ru1—Ru2—C15—C20−0.7 (9)
C3—Ru1—N1—O118.3 (14)N3—Ru3—C21—C25−86.9 (4)
Ru2—Ru1—N1—O1−175.8 (9)N4—Ru3—C21—C25143.1 (4)
N2—Ru1—N1—Ru22.1 (2)C24—Ru3—C21—C2537.5 (4)
C4—Ru1—N1—Ru2132.1 (3)C22—Ru3—C21—C25117.8 (5)
C2—Ru1—N1—Ru2−137.4 (3)C23—Ru3—C21—C2580.2 (4)
C5—Ru1—N1—Ru2156.0 (2)Ru4—Ru3—C21—C25−118.8 (3)
C1—Ru1—N1—Ru2−166.2 (2)N3—Ru3—C21—C22155.2 (4)
C3—Ru1—N1—Ru2−166.0 (8)N4—Ru3—C21—C2225.3 (6)
N2—Ru2—N1—O1173.6 (8)C24—Ru3—C21—C22−80.3 (4)
C15—Ru2—N1—O120.1 (8)C25—Ru3—C21—C22−117.8 (5)
C14—Ru2—N1—O142.9 (9)C23—Ru3—C21—C22−37.7 (4)
C12—Ru2—N1—O1−46.6 (8)Ru4—Ru3—C21—C22123.4 (4)
C11—Ru2—N1—O1−18.1 (8)N3—Ru3—C21—C2633.2 (6)
C13—Ru2—N1—O1−21.2 (14)N4—Ru3—C21—C26−96.8 (7)
Ru1—Ru2—N1—O1175.7 (9)C24—Ru3—C21—C26157.6 (7)
N2—Ru2—N1—Ru1−2.1 (2)C22—Ru3—C21—C26−122.1 (7)
C15—Ru2—N1—Ru1−155.7 (2)C25—Ru3—C21—C26120.1 (7)
C14—Ru2—N1—Ru1−132.8 (3)C23—Ru3—C21—C26−159.7 (7)
C12—Ru2—N1—Ru1137.6 (2)Ru4—Ru3—C21—C261.3 (8)
C11—Ru2—N1—Ru1166.2 (2)C25—C21—C22—C230.9 (7)
C13—Ru2—N1—Ru1163.1 (8)C26—C21—C22—C23−177.0 (6)
N1—Ru2—N2—O2−175.0 (7)Ru3—C21—C22—C2362.9 (4)
C15—Ru2—N2—O2−45.3 (10)C25—C21—C22—C27176.4 (6)
C14—Ru2—N2—O2−28.4 (8)C26—C21—C22—C27−1.5 (10)
C12—Ru2—N2—O241.9 (8)Ru3—C21—C22—C27−121.6 (7)
C11—Ru2—N2—O239.1 (11)C25—C21—C22—Ru3−62.0 (4)
C13—Ru2—N2—O29.5 (8)C26—C21—C22—Ru3120.1 (6)
Ru1—Ru2—N2—O2−177.1 (8)N3—Ru3—C22—C23−154.0 (4)
N1—Ru2—N2—Ru12.1 (2)N4—Ru3—C22—C2377.5 (4)
C15—Ru2—N2—Ru1131.8 (4)C21—Ru3—C22—C23−116.9 (6)
C14—Ru2—N2—Ru1148.7 (2)C24—Ru3—C22—C23−36.9 (4)
C12—Ru2—N2—Ru1−141.0 (2)C25—Ru3—C22—C23−79.6 (4)
C11—Ru2—N2—Ru1−143.8 (6)Ru4—Ru3—C22—C23122.2 (4)
C13—Ru2—N2—Ru1−173.4 (2)N3—Ru3—C22—C21−37.1 (5)
N1—Ru1—N2—O2175.0 (7)N4—Ru3—C22—C21−165.6 (4)
C4—Ru1—N2—O228.9 (8)C24—Ru3—C22—C2180.0 (4)
C2—Ru1—N2—O2−41.0 (8)C25—Ru3—C22—C2137.2 (4)
C5—Ru1—N2—O245.2 (9)C23—Ru3—C22—C21116.9 (6)
C1—Ru1—N2—O2−37.8 (11)Ru4—Ru3—C22—C21−121.0 (4)
C3—Ru1—N2—O2−8.5 (7)N3—Ru3—C22—C2785.7 (7)
Ru2—Ru1—N2—O2177.1 (8)N4—Ru3—C22—C27−42.8 (7)
N1—Ru1—N2—Ru2−2.1 (2)C21—Ru3—C22—C27122.8 (8)
C4—Ru1—N2—Ru2−148.2 (2)C24—Ru3—C22—C27−157.3 (7)
C2—Ru1—N2—Ru2141.9 (2)C25—Ru3—C22—C27160.0 (7)
C5—Ru1—N2—Ru2−132.0 (4)C23—Ru3—C22—C27−120.4 (8)
C1—Ru1—N2—Ru2145.0 (6)Ru4—Ru3—C22—C271.8 (9)
C3—Ru1—N2—Ru2174.4 (2)C21—C22—C23—C24−1.9 (7)
N4—Ru4—N3—O3−176.6 (7)C27—C22—C23—C24−177.6 (6)
C35—Ru4—N3—O321.4 (8)Ru3—C22—C23—C2460.3 (4)
C34—Ru4—N3—O347.1 (8)C21—C22—C23—C28177.6 (6)
C31—Ru4—N3—O3−16.8 (8)C27—C22—C23—C281.9 (10)
C32—Ru4—N3—O3−40.9 (9)Ru3—C22—C23—C28−120.2 (6)
C33—Ru4—N3—O36.4 (14)C21—C22—C23—Ru3−62.2 (4)
Ru3—Ru4—N3—O3−178.6 (8)C27—C22—C23—Ru3122.1 (6)
N4—Ru4—N3—Ru32.0 (2)N3—Ru3—C23—C2284.9 (9)
C35—Ru4—N3—Ru3−160.0 (2)N4—Ru3—C23—C22−112.6 (4)
C34—Ru4—N3—Ru3−134.3 (3)C21—Ru3—C23—C2238.1 (4)
C31—Ru4—N3—Ru3161.8 (2)C24—Ru3—C23—C22118.9 (6)
C32—Ru4—N3—Ru3137.7 (3)C25—Ru3—C23—C2280.6 (4)
C33—Ru4—N3—Ru3−175.0 (9)Ru4—Ru3—C23—C22−122.6 (4)
N4—Ru3—N3—O3176.6 (8)N3—Ru3—C23—C24−34.0 (10)
C21—Ru3—N3—O321.4 (8)N4—Ru3—C23—C24128.5 (4)
C24—Ru3—N3—O3−46.3 (8)C21—Ru3—C23—C24−80.8 (4)
C22—Ru3—N3—O343.9 (9)C22—Ru3—C23—C24−118.9 (6)
C25—Ru3—N3—O3−16.9 (8)C25—Ru3—C23—C24−38.3 (4)
C23—Ru3—N3—O3−20.8 (14)Ru4—Ru3—C23—C24118.6 (4)
Ru4—Ru3—N3—O3178.6 (9)N3—Ru3—C23—C28−155.0 (8)
N4—Ru3—N3—Ru4−2.0 (2)N4—Ru3—C23—C287.6 (7)
C21—Ru3—N3—Ru4−157.2 (2)C21—Ru3—C23—C28158.2 (7)
C24—Ru3—N3—Ru4135.1 (3)C24—Ru3—C23—C28−121.0 (8)
C22—Ru3—N3—Ru4−134.6 (3)C22—Ru3—C23—C28120.1 (8)
C25—Ru3—N3—Ru4164.5 (2)C25—Ru3—C23—C28−159.3 (7)
C23—Ru3—N3—Ru4160.6 (7)Ru4—Ru3—C23—C28−2.4 (9)
N3—Ru3—N4—O4−177.9 (8)C22—C23—C24—C252.2 (7)
C21—Ru3—N4—O4−46.2 (10)C28—C23—C24—C25−177.3 (6)
C24—Ru3—N4—O441.0 (9)Ru3—C23—C24—C2562.7 (4)
C22—Ru3—N4—O4−29.9 (8)C22—C23—C24—C29176.5 (6)
C25—Ru3—N4—O440.7 (12)C28—C23—C24—C29−3.0 (11)
C23—Ru3—N4—O47.2 (8)Ru3—C23—C24—C29−123.0 (7)
Ru4—Ru3—N4—O4−179.9 (9)C22—C23—C24—Ru3−60.5 (4)
N3—Ru3—N4—Ru42.0 (2)C28—C23—C24—Ru3120.0 (6)
C21—Ru3—N4—Ru4133.7 (4)N3—Ru3—C24—C23168.0 (4)
C24—Ru3—N4—Ru4−139.1 (2)N4—Ru3—C24—C23−63.4 (5)
C22—Ru3—N4—Ru4150.0 (2)C21—Ru3—C24—C2379.2 (4)
C25—Ru3—N4—Ru4−139.4 (5)C22—Ru3—C24—C2336.6 (4)
C23—Ru3—N4—Ru4−172.9 (2)C25—Ru3—C24—C23116.4 (6)
N3—Ru4—N4—O4177.9 (8)Ru4—Ru3—C24—C23−123.7 (4)
C35—Ru4—N4—O4−49.2 (11)N3—Ru3—C24—C2551.7 (5)
C34—Ru4—N4—O4−38.8 (9)N4—Ru3—C24—C25−179.8 (4)
C31—Ru4—N4—O446.7 (11)C21—Ru3—C24—C25−37.2 (4)
C32—Ru4—N4—O433.1 (9)C22—Ru3—C24—C25−79.8 (4)
C33—Ru4—N4—O4−3.0 (9)C23—Ru3—C24—C25−116.4 (6)
Ru3—Ru4—N4—O4179.9 (9)Ru4—Ru3—C24—C25119.9 (4)
N3—Ru4—N4—Ru3−2.0 (2)N3—Ru3—C24—C29−69.4 (7)
C35—Ru4—N4—Ru3130.9 (5)N4—Ru3—C24—C2959.1 (7)
C34—Ru4—N4—Ru3141.3 (3)C21—Ru3—C24—C29−158.3 (7)
C31—Ru4—N4—Ru3−133.2 (5)C22—Ru3—C24—C29159.1 (7)
C32—Ru4—N4—Ru3−146.8 (3)C25—Ru3—C24—C29−121.1 (8)
C33—Ru4—N4—Ru3177.0 (3)C23—Ru3—C24—C29122.6 (8)
N1—Ru1—C1—C5−99.4 (4)Ru4—Ru3—C24—C29−1.2 (8)
N2—Ru1—C1—C5113.8 (7)C22—C21—C25—C240.5 (7)
C4—Ru1—C1—C538.0 (4)C26—C21—C25—C24178.4 (6)
C2—Ru1—C1—C5118.2 (6)Ru3—C21—C25—C24−61.4 (4)
C3—Ru1—C1—C580.6 (4)C22—C21—C25—C30−178.6 (6)
Ru2—Ru1—C1—C5−118.9 (4)C26—C21—C25—C30−0.7 (10)
N1—Ru1—C1—C2142.4 (4)Ru3—C21—C25—C30119.5 (6)
N2—Ru1—C1—C2−4.4 (8)C22—C21—C25—Ru361.9 (4)
C4—Ru1—C1—C2−80.1 (4)C26—C21—C25—Ru3−120.2 (6)
C5—Ru1—C1—C2−118.2 (6)C23—C24—C25—C21−1.7 (7)
C3—Ru1—C1—C2−37.5 (4)C29—C24—C25—C21−176.1 (6)
Ru2—Ru1—C1—C2122.9 (4)Ru3—C24—C25—C2161.5 (4)
N1—Ru1—C1—C620.6 (6)C23—C24—C25—C30177.4 (6)
N2—Ru1—C1—C6−126.2 (7)C29—C24—C25—C303.0 (10)
C4—Ru1—C1—C6158.1 (6)Ru3—C24—C25—C30−119.5 (6)
C2—Ru1—C1—C6−121.8 (7)C23—C24—C25—Ru3−63.2 (4)
C5—Ru1—C1—C6120.0 (7)C29—C24—C25—Ru3122.5 (7)
C3—Ru1—C1—C6−159.3 (6)N3—Ru3—C25—C21101.5 (4)
Ru2—Ru1—C1—C61.1 (8)N4—Ru3—C25—C21−117.4 (7)
C5—C1—C2—C31.9 (7)C24—Ru3—C25—C21−117.9 (5)
C6—C1—C2—C3−178.3 (6)C22—Ru3—C25—C21−37.5 (4)
Ru1—C1—C2—C363.5 (4)C23—Ru3—C25—C21−79.8 (4)
C5—C1—C2—C7175.4 (6)Ru4—Ru3—C25—C21122.1 (3)
C6—C1—C2—C7−4.8 (10)N3—Ru3—C25—C24−140.6 (4)
Ru1—C1—C2—C7−123.0 (6)N4—Ru3—C25—C240.5 (8)
C5—C1—C2—Ru1−61.5 (4)C21—Ru3—C25—C24117.9 (5)
C6—C1—C2—Ru1118.3 (6)C22—Ru3—C25—C2480.4 (4)
N1—Ru1—C2—C3−166.8 (4)C23—Ru3—C25—C2438.1 (4)
N2—Ru1—C2—C361.6 (5)Ru4—Ru3—C25—C24−120.1 (4)
C4—Ru1—C2—C3−36.8 (4)N3—Ru3—C25—C30−18.5 (6)
C5—Ru1—C2—C3−80.0 (4)N4—Ru3—C25—C30122.6 (7)
C1—Ru1—C2—C3−116.6 (6)C21—Ru3—C25—C30−120.0 (7)
Ru2—Ru1—C2—C3121.2 (4)C24—Ru3—C25—C30122.1 (7)
N1—Ru1—C2—C1−50.2 (5)C22—Ru3—C25—C30−157.5 (6)
N2—Ru1—C2—C1178.1 (4)C23—Ru3—C25—C30160.2 (6)
C4—Ru1—C2—C179.8 (4)Ru4—Ru3—C25—C302.1 (7)
C5—Ru1—C2—C136.6 (4)N3—Ru4—C31—C3592.1 (4)
C3—Ru1—C2—C1116.6 (6)N4—Ru4—C31—C35−137.3 (6)
Ru2—Ru1—C2—C1−122.2 (4)C34—Ru4—C31—C35−37.6 (4)
N1—Ru1—C2—C771.8 (7)C32—Ru4—C31—C35−117.3 (6)
N2—Ru1—C2—C7−59.9 (7)C33—Ru4—C31—C35−79.9 (5)
C4—Ru1—C2—C7−158.3 (7)Ru3—Ru4—C31—C35116.4 (4)
C5—Ru1—C2—C7158.6 (7)N3—Ru4—C31—C32−150.6 (5)
C1—Ru1—C2—C7122.0 (8)N4—Ru4—C31—C32−20.0 (8)
C3—Ru1—C2—C7−121.5 (8)C35—Ru4—C31—C32117.3 (6)
Ru2—Ru1—C2—C7−0.2 (8)C34—Ru4—C31—C3279.6 (5)
C1—C2—C3—C4−2.9 (7)C33—Ru4—C31—C3237.4 (5)
C7—C2—C3—C4−176.5 (6)Ru3—Ru4—C31—C32−126.4 (5)
Ru1—C2—C3—C460.2 (4)N3—Ru4—C31—C36−27.8 (8)
C1—C2—C3—C8178.6 (6)N4—Ru4—C31—C36102.8 (9)
C7—C2—C3—C85.0 (10)C35—Ru4—C31—C36−119.9 (9)
Ru1—C2—C3—C8−118.3 (6)C34—Ru4—C31—C36−157.6 (8)
C1—C2—C3—Ru1−63.1 (4)C32—Ru4—C31—C36122.8 (9)
C7—C2—C3—Ru1123.3 (7)C33—Ru4—C31—C36160.2 (8)
N1—Ru1—C3—C238.1 (10)Ru3—Ru4—C31—C36−3.6 (10)
N2—Ru1—C3—C2−129.9 (4)C35—C31—C32—C33−0.8 (7)
C4—Ru1—C3—C2119.0 (6)C36—C31—C32—C33178.7 (7)
C5—Ru1—C3—C280.2 (4)Ru4—C31—C32—C33−62.4 (5)
C1—Ru1—C3—C238.3 (4)C35—C31—C32—C37−175.3 (7)
Ru2—Ru1—C3—C2−122.2 (4)C36—C31—C32—C374.2 (12)
N1—Ru1—C3—C4−80.9 (10)Ru4—C31—C32—C37123.1 (8)
N2—Ru1—C3—C4111.1 (4)C35—C31—C32—Ru461.6 (4)
C2—Ru1—C3—C4−119.0 (6)C36—C31—C32—Ru4−118.9 (7)
C5—Ru1—C3—C4−38.8 (4)N3—Ru4—C32—C33157.7 (4)
C1—Ru1—C3—C4−80.7 (4)N4—Ru4—C32—C33−72.9 (5)
Ru2—Ru1—C3—C4118.8 (4)C35—Ru4—C32—C3379.6 (5)
N1—Ru1—C3—C8160.2 (8)C34—Ru4—C32—C3336.7 (4)
N2—Ru1—C3—C8−7.8 (6)C31—Ru4—C32—C33117.0 (6)
C4—Ru1—C3—C8−118.9 (8)Ru3—Ru4—C32—C33−125.3 (5)
C2—Ru1—C3—C8122.1 (8)N3—Ru4—C32—C3140.7 (6)
C5—Ru1—C3—C8−157.7 (7)N4—Ru4—C32—C31170.1 (4)
C1—Ru1—C3—C8160.4 (7)C35—Ru4—C32—C31−37.4 (4)
Ru2—Ru1—C3—C8−0.1 (8)C34—Ru4—C32—C31−80.3 (5)
C2—C3—C4—C52.8 (7)C33—Ru4—C32—C31−117.0 (6)
C8—C3—C4—C5−178.7 (6)Ru3—Ru4—C32—C31117.7 (4)
Ru1—C3—C4—C563.3 (4)N3—Ru4—C32—C37−78.9 (12)
C2—C3—C4—C9−180.0 (6)N4—Ru4—C32—C3750.5 (12)
C8—C3—C4—C9−1.4 (10)C35—Ru4—C32—C37−157.0 (12)
Ru1—C3—C4—C9−119.4 (6)C34—Ru4—C32—C37160.1 (12)
C2—C3—C4—Ru1−60.5 (4)C31—Ru4—C32—C37−119.6 (13)
C8—C3—C4—Ru1118.0 (6)C33—Ru4—C32—C37123.4 (13)
N1—Ru1—C4—C3155.3 (4)Ru3—Ru4—C32—C37−1.9 (15)
N2—Ru1—C4—C3−78.7 (4)C31—C32—C33—C341.1 (8)
C2—Ru1—C4—C336.3 (4)C37—C32—C33—C34175.4 (8)
C5—Ru1—C4—C3115.9 (5)Ru4—C32—C33—C34−60.6 (5)
C1—Ru1—C4—C379.1 (4)C31—C32—C33—C38−179.2 (7)
Ru2—Ru1—C4—C3−122.9 (4)C37—C32—C33—C38−4.9 (12)
N1—Ru1—C4—C539.5 (5)Ru4—C32—C33—C38119.1 (8)
N2—Ru1—C4—C5165.4 (4)C31—C32—C33—Ru461.7 (5)
C2—Ru1—C4—C5−79.6 (4)C37—C32—C33—Ru4−123.9 (8)
C1—Ru1—C4—C5−36.8 (4)N3—Ru4—C33—C32−63.9 (11)
C3—Ru1—C4—C5−115.9 (5)N4—Ru4—C33—C32119.1 (5)
Ru2—Ru1—C4—C5121.2 (4)C35—Ru4—C33—C32−80.6 (5)
N1—Ru1—C4—C9−82.9 (7)C34—Ru4—C33—C32−118.9 (6)
N2—Ru1—C4—C943.1 (7)C31—Ru4—C33—C32−38.2 (4)
C2—Ru1—C4—C9158.1 (7)Ru3—Ru4—C33—C32123.5 (5)
C5—Ru1—C4—C9−122.4 (8)N3—Ru4—C33—C3455.0 (12)
C1—Ru1—C4—C9−159.2 (7)N4—Ru4—C33—C34−122.0 (4)
C3—Ru1—C4—C9121.8 (8)C35—Ru4—C33—C3438.3 (4)
Ru2—Ru1—C4—C9−1.2 (9)C31—Ru4—C33—C3480.8 (4)
C2—C1—C5—C4−0.2 (7)C32—Ru4—C33—C34118.9 (6)
C6—C1—C5—C4180.0 (6)Ru3—Ru4—C33—C34−117.6 (4)
Ru1—C1—C5—C4−61.3 (4)N3—Ru4—C33—C38174.2 (9)
C2—C1—C5—C10−178.6 (6)N4—Ru4—C33—C38−2.8 (10)
C6—C1—C5—C101.6 (10)C35—Ru4—C33—C38157.5 (11)
Ru1—C1—C5—C10120.4 (6)C34—Ru4—C33—C38119.2 (12)
C2—C1—C5—Ru161.1 (4)C31—Ru4—C33—C38−160.1 (11)
C6—C1—C5—Ru1−118.7 (6)C32—Ru4—C33—C38−121.9 (12)
C3—C4—C5—C1−1.6 (7)Ru3—Ru4—C33—C381.5 (13)
C9—C4—C5—C1−178.8 (6)C32—C33—C34—C35−1.0 (7)
Ru1—C4—C5—C162.2 (4)C38—C33—C34—C35179.3 (7)
C3—C4—C5—C10176.7 (6)Ru4—C33—C34—C35−62.0 (4)
C9—C4—C5—C10−0.5 (10)C32—C33—C34—C39−175.8 (7)
Ru1—C4—C5—C10−119.5 (7)C38—C33—C34—C394.5 (11)
C3—C4—C5—Ru1−63.8 (4)Ru4—C33—C34—C39123.1 (7)
C9—C4—C5—Ru1119.0 (6)C32—C33—C34—Ru461.1 (5)
N1—Ru1—C5—C189.1 (4)C38—C33—C34—Ru4−118.6 (7)
N2—Ru1—C5—C1−142.7 (4)N3—Ru4—C34—C33−160.4 (4)
C4—Ru1—C5—C1−117.6 (5)N4—Ru4—C34—C3370.4 (5)
C2—Ru1—C5—C1−37.5 (4)C35—Ru4—C34—C33−116.6 (6)
C3—Ru1—C5—C1−79.4 (4)C31—Ru4—C34—C33−79.4 (5)
Ru2—Ru1—C5—C1122.2 (4)C32—Ru4—C34—C33−36.5 (5)
N1—Ru1—C5—C4−153.4 (4)Ru3—Ru4—C34—C33127.0 (5)
N2—Ru1—C5—C4−25.2 (6)N3—Ru4—C34—C35−43.8 (5)
C2—Ru1—C5—C480.1 (4)N4—Ru4—C34—C35−173.0 (4)
C1—Ru1—C5—C4117.6 (5)C31—Ru4—C34—C3537.2 (4)
C3—Ru1—C5—C438.2 (4)C32—Ru4—C34—C3580.1 (5)
Ru2—Ru1—C5—C4−120.2 (4)C33—Ru4—C34—C35116.6 (6)
N1—Ru1—C5—C10−30.6 (7)Ru3—Ru4—C34—C35−116.5 (4)
N2—Ru1—C5—C1097.6 (7)N3—Ru4—C34—C3974.7 (8)
C4—Ru1—C5—C10122.8 (8)N4—Ru4—C34—C39−54.5 (8)
C2—Ru1—C5—C10−157.2 (7)C35—Ru4—C34—C39118.5 (9)
C1—Ru1—C5—C10−119.7 (8)C31—Ru4—C34—C39155.7 (9)
C3—Ru1—C5—C10160.9 (8)C32—Ru4—C34—C39−161.4 (9)
Ru2—Ru1—C5—C102.6 (9)C33—Ru4—C34—C39−124.9 (9)
N2—Ru2—C11—C15−113.6 (7)Ru3—Ru4—C34—C392.1 (10)
N1—Ru2—C11—C15100.8 (4)C32—C31—C35—C340.2 (7)
C14—Ru2—C11—C15−37.3 (4)C36—C31—C35—C34−179.3 (6)
C12—Ru2—C11—C15−117.3 (6)Ru4—C31—C35—C3462.3 (4)
C13—Ru2—C11—C15−80.2 (4)C32—C31—C35—C40179.4 (6)
Ru1—Ru2—C11—C15119.4 (4)C36—C31—C35—C40−0.1 (10)
N2—Ru2—C11—C123.8 (8)Ru4—C31—C35—C40−118.5 (6)
N1—Ru2—C11—C12−141.8 (4)C32—C31—C35—Ru4−62.1 (5)
C15—Ru2—C11—C12117.3 (6)C36—C31—C35—Ru4118.3 (7)
C14—Ru2—C11—C1280.0 (4)C33—C34—C35—C310.5 (7)
C13—Ru2—C11—C1237.1 (4)C39—C34—C35—C31175.6 (6)
Ru1—Ru2—C11—C12−123.3 (4)Ru4—C34—C35—C31−62.6 (4)
N2—Ru2—C11—C16126.0 (7)C33—C34—C35—C40−178.7 (6)
N1—Ru2—C11—C16−19.6 (6)C39—C34—C35—C40−3.6 (10)
C15—Ru2—C11—C16−120.4 (7)Ru4—C34—C35—C40118.2 (6)
C14—Ru2—C11—C16−157.8 (6)C33—C34—C35—Ru463.1 (5)
C12—Ru2—C11—C16122.2 (7)C39—C34—C35—Ru4−121.8 (6)
C13—Ru2—C11—C16159.3 (6)N3—Ru4—C35—C31−94.8 (4)
Ru1—Ru2—C11—C16−1.0 (7)N4—Ru4—C35—C31132.7 (6)
C15—C11—C12—C13−1.8 (7)C34—Ru4—C35—C31117.7 (6)
C16—C11—C12—C13179.1 (6)C32—Ru4—C35—C3137.9 (5)
Ru2—C11—C12—C13−62.9 (4)C33—Ru4—C35—C3180.0 (5)
C15—C11—C12—C17−175.7 (6)Ru3—Ru4—C35—C31−120.4 (4)
C16—C11—C12—C175.2 (10)N3—Ru4—C35—C34147.5 (4)
Ru2—C11—C12—C17123.3 (6)N4—Ru4—C35—C3415.0 (8)
C15—C11—C12—Ru261.1 (4)C31—Ru4—C35—C34−117.7 (6)
C16—C11—C12—Ru2−118.0 (6)C32—Ru4—C35—C34−79.8 (5)
N2—Ru2—C12—C13−61.0 (4)C33—Ru4—C35—C34−37.7 (5)
N1—Ru2—C12—C13167.7 (4)Ru3—Ru4—C35—C34121.8 (4)
C15—Ru2—C12—C1380.1 (4)N3—Ru4—C35—C4025.9 (6)
C14—Ru2—C12—C1337.4 (4)N4—Ru4—C35—C40−106.7 (7)
C11—Ru2—C12—C13117.5 (6)C34—Ru4—C35—C40−121.6 (8)
Ru1—Ru2—C12—C13−122.9 (4)C31—Ru4—C35—C40120.6 (8)
N2—Ru2—C12—C11−178.4 (4)C32—Ru4—C35—C40158.6 (7)
N1—Ru2—C12—C1150.2 (5)C33—Ru4—C35—C40−159.4 (7)
C15—Ru2—C12—C11−37.4 (4)Ru3—Ru4—C35—C400.2 (7)
references
References top

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