Acta Cryst. (2007). E63, m2486-m2487  [ doi:10.1107/S1600536807042833 ]

Bis(4,6-dimethyl-2-pyrimidinethiolato-²N,S)bis(methanol-O)manganese(II)

H.-Y. Li, H.-X. Li, X.-Y. Tang, Y. Chen and J.-P. Lang

Abstract: In the title molecular compound, [Mn(C₆H₇N₂S)₂(CH₄O)₂], the Mn atom is octahedrally coordinated by two N atoms and two S atoms from two 4,6-dimethyl-2-pyrimidinethiolate anions and two O atoms from two methanol molecules. The molecule lies on a twofold rotation axis. The methanol molecule engages in hydrogen bonding with the N atom of an adjacent molecule to form a chain that runs along the c axis.

Online 8 September 2007

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