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Acta Cryst. (2007). E63, m2484  [ doi:10.1107/S1600536807043279 ]

Bromido[(1,2,5,6-[eta])-1,3,5,7-cyclooctatetraene]methylplatinum(II)

A.-R. Song, I.-C. Hwang and K. Ha

Abstract: In the title complex, [PtBr(CH3)(C8H8)], the PtII centre lies in a square-planar environment defined by the Br and methyl C atoms and the midpoints of the two [pi]-coordinated double bonds of 1,3,5,7-cyclooctatetraene. Because of the different trans influences of the Br atom and the methyl group, the Pt-C bonds trans to the methyl group are longer than those trans to the Br atom.

Online 8 September 2007


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