[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Buy article online]

[Contents scheme]

Acta Cryst. (2007). E63, m2603  [ doi:10.1107/S1600536807046545 ]

catena-Poly[[dichloridozinc(II)]-[mu]-1-carboxylatomethyl-3-methylimidazolium-[kappa]2O:O']

X. Shi, J. Zhang, T.-K. Ying and G.-L. Zhao

Abstract: The crystal structure of the title compound, [ZnCl2(C6H8N2O2)]n, consists of a zigzag chain in which adjacent ZnCl2 groups are bridged by 1-carboxylatomethyl-3-methylimidazolium through its two O atoms. The environment around the Zn atom can be described as a cis-ZnO2Cl2 tetrahedron. The formation of the chain is strengthened by [pi]-[pi] stacking interactions between adjacent imidazole ring planes ([pi]-[pi] distance = 3.618 Å).

Online 26 September 2007


Copyright © International Union of Crystallography
IUCr Webmaster