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Acta Cryst. (2007). E63, m2448  [ doi:10.1107/S1600536807042079 ]

Di-[mu]-methoxido-[kappa]4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-[kappa]N2)copper(II)] bis(perchlorate)

H. He and A. G. Sykes

Abstract: In the title complex, [Cu(CH3O)2(C40H40N8)](ClO4)2, two copper ions are bridged by two methoxide O atoms. Each CuII is further coordinated by two neutral 3-methyl-5-phenyl-1H-pyrazole ligands and adopts a distorted square-planar geometry. The two perchlorate anions lie on opposite sides of the Cu2O2 plane and there is evidence for interaction between two of the O atoms from each perchlorate anion with the CuII centers.

Online 1 September 2007


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