Acta Cryst. (2007). E63, m2496-m2497 [ doi:10.1107/S1600536807043267 ]
Abstract: The asymmetric unit of the title compound, [Cu2(C12H17N2O2)2(N3)(-N3)(H2O)]·H2O, consists of a dinuclear complex molecule and a solvent water molecule. One Cu atom is six-coordinated by the phenol O atom and by one imine and one amine N atoms from one Schiff base ligand, the phenol and ether O atoms of the second Schiff base, together with a terminal N atom of the bridging azide ligand, in an octahedral geometry. The coordination environment of the second Cu atom contains a phenol O and imine and amine N atoms from one Schiff base ligand, two further N atoms, one from the bridging and the other from a terminal azide ligand, and a coordinated water molecule, also in an octahedral geometry. The crystal structure involves O-HN and O-HO hydrogen bonds.
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