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Acta Cryst. (2007). E63, m2542 [ doi:10.1107/S1600536807044261 ]
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3-ethylidyne-triangulo-tricobalt(I)(3 Co-Co)Abstract: The title molecule, [Co3(C2H3)(C5H9N)3(CO)6] or [Co3(3-CCH3)(CNtBu)3(CO)6], lies on a threefold rotation axis. The three isonitrile ligands each occupy an equatorial site on each of the three Co atoms. The average Co-Co bond length is 2.4769 (6) Å. The tert-butyl groups are disordered over two orientations, with site occupancies of ca 0.6:0.4.
Online 21 September 2007
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