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Acta Cryst. (2007). E63, o4021 [ doi:10.1107/S1600536807042845 ]
Abstract: Chlorothiazide forms a 1:2 solvate with formic acid (systematic name: 6-chloro-2H-1,2,4-benzothiadiazine-7-sulfonamide 1,1-dioxide methanoic acid disolvate), C7H6ClN3O4S2·2CH2O2. The compound crystallizes with one chlorothiazide molecule and two solvent molecules in the asymmetric unit and displays an extensive hydrogen-bonding network.
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