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Acta Cryst. (2007). E63, m3096  [ doi:10.1107/S1600536807059090 ]

[mu]-Fumarato-[kappa]4O,O';O'',O'''-bis[aqua(2,9-dimethyl-1,10-phenanthroline-[kappa]2N,N)(nitrato-[kappa]2O,O')manganese(II)]

L. Li, H. Zhang, M.-L. Zhang and S. Bi

Abstract: In the centrosymmetric title compound, [Mn2(C4H2O4)(NO3)2(C14H12N2)2(H2O)2], each Mn atom is six-coordinate in a distorted octahedral geometry. Molecules form stacks by [pi]-[pi] interactions (centroid-centroid distances of 3.826, 3.708 and 3.719 Å). The water molecules act as donors to form O-H...O hydrogen bonds. Moreover, the molecules are linked into chains along the a axis by C-H...O intermolecular hydrogen bonds.

Online 23 November 2007


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