Acta Cryst. (2007). E63, m3071  [ doi:10.1107/S160053680705845X ]

(2,2'-Bipyridine)saccharinatosilver(I)

V. T. Yilmaz, S. Hamamci and W. T. A. Harrison

Abstract: The title complex, [Ag(C₇H₄NO₃S)(C₁₀H₈N₂)], has a mononuclear structure in which the Ag^I ion is coordinated by two N atoms from 2,2'-bipyridine and one N atom from saccharinate, forming a distorted T-shaped (or trigonal-planar) AgN₃ arrangement. The bite angle of bpy is 71.69 (6)°, which contributes significantly to the distortion of the coordination geometry. Molecules are connected by C-HO and (bpy)-(bpy) interactions with a centroid-centroid separation of 3.6741 (13) Å.

Online 21 November 2007

Copyright © International Union of Crystallography
IUCr Webmaster