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Acta Cryst. (2007). E63, m3035  [ doi:10.1107/S1600536807049550 ]

catena-Poly[[(6-aminonaphthalene-1-sulfonato-[kappa]O)silver(I)]-[mu]-2,3,5,6-tetramethylpyrazine-[kappa]2N:N']

H.-Y. Liu, J.-C. Ma and Y.-Y. Liu

Abstract: In the title compound, [Ag(C10H8NO3S)(C8H12N2)]n, the Ag+ cation is three-coordinated by two N atoms from two 2,3,5,6-tetramethylpyrazine ligands and one O atom from a 7-aminonaphthalene-1-sulfonate anion. The 2,3,5,6-tetramethylpyrazine ligand acts as a bridging bidentate ligand, linking the AgI centres into a one-dimensional chain. The chains are interconnected via intermolecular N-H...O hydrogen bonds and C-H...[pi] interactions, resulting in the formation of a three-dimensional framework.

Online 16 November 2007


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