Acta Cryst. (2007). E63, m3027  [ doi:10.1107/S1600536807057121 ]

catena-Poly[[[bis(triphenylphosphine)silver(I)]--6-aminonaphthalene-1-sulfonato-²O:N] monohydrate]

H. Wu, Y.-Y. Liu and H.-Y. Bai

Abstract: In the title compound, {[Ag(C₁₀H₈NO₃S)(C₁₈H₁₅P)₂]·H₂O}_n, each Ag^I cation is four coordinated by two P atoms from two different triphenylphosphine ligands, and by one N atom and one sulfonate O atom from different 6-aminonaphthalene-1-sulfonate anions in a distorted tetrahedral geometry. Each 6-aminonaphthalene-1-sulfonate ligand bridges two Ag^I centers, resulting in the formation of polymeric chains parallel to the a axis. Intermolecular O-HO and N-HO hydrogen bonds contribute to the crystal packing stability. One phenyl ring is disordered over two positions; the site occupancies are 0.68 and 0.32.

Online 14 November 2007

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