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Acta Cryst. (2007). E63, m3027    [ doi:10.1107/S1600536807057121 ]

catena-Poly[[[bis(triphenylphosphine)silver(I)]-[mu]-6-aminonaphthalene-1-sulfonato-[kappa]2O:N] monohydrate]

H. Wu, Y.-Y. Liu and H.-Y. Bai

Abstract top

In the title compound, {[Ag(C10H8NO3S)(C18H15P)2]·H2O}n, each AgI cation is four coordinated by two P atoms from two different triphenylphosphine ligands, and by one N atom and one sulfonate O atom from different 6-aminonaphthalene-1-sulfonate anions in a distorted tetrahedral geometry. Each 6-aminonaphthalene-1-sulfonate ligand bridges two AgI centers, resulting in the formation of polymeric chains parallel to the a axis. Intermolecular O-H...O and N-H...O hydrogen bonds contribute to the crystal packing stability. One phenyl ring is disordered over two positions; the site occupancies are 0.68 and 0.32.

Comment top

In the title compound, (I), each AgI cation is four-coordinated by two P atoms from two triphenylphosphine ligands, one N atom and one O atom from the different 6-aminonaphthalene-1-sulfonate anions (Fig. 1). The Ag—O (sulfonate) distance in (I) is similar to the equivalent value in a related compound (Wang et al., 2007).

There are two intermolecular N—H···O hydrogen bonds involving the amino N atom and two sulfonate O atoms among the adjacent 6-aminonaphthalene-1-sulfonate anions (Table 1), and the whole structure displays a double chain supramolecular framework, The lattice water molecule connects the units via hydrogen bond (Fig. 2).

Related literature top

For related literature, see: Wang et al. (2007).

Experimental top

An aqueous solution (10 ml) of 6-aminonaphthalene-1-sulfonic acid (0.1115 g, 0.5 mmol) was added to solid Ag2CO3 (0.069 g, 0.25 mmol) and stirred for several minutes until no further CO2 was given off; triphenylphosphine (0.113 g, 0.5 mmol) in acetonitrile (10 ml) was then added and a white precipitate formed. The precipitate was dissolved by dropwise addition of an aqueous solution of NH3 (14 M). Colourless blocks of (I) were obtained by evaporation of the solution for several days at room temperature.

Refinement top

C-bound H-atoms were geometrically positioned (C—H 0.93 Å) and refined using a riding model, with Uiso = 1.2Ueq (C). The H atoms of the amino group and water molecule were located in a difference map and refined freely, with Uiso(H) = 1.2Ueq (N, O). One phenyl ring in triphenylphosphine ligand was treated as disordered between two orientations with the refined occupancies of 0.677 (15) and 0.323 (15), respectively.

Computing details top

Data collection: PROCESS-AUTO (Rigaku Corporation, 1998); cell refinement: PROCESS-AUTO (Rigaku Corporation, 1998); data reduction: PROCESS-AUTO (Rigaku Corporation, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL-Plus (Sheldrick, 1990); software used to prepare material for publication: SHELXL97 (Sheldrick, 1997).

Figures top
[Figure 1] Fig. 1. A portion of the polymeric chain in (I), showing the 30% probability displacement ellipsoids, crystalline water molecule and the atomic numbering [symmetry code: (A) −1 + x, y, z]. H atoms have been omitted for clarity.
[Figure 2] Fig. 2. The double-chain framework of (I), formed through hydrogen-bonding (dashed lines) interactions. The atoms of H not involved in hydrogen bonding interactions have been omitted.
catena-Poly[[[bis(triphenylphosphine)silver(I)]-µ-6- aminonaphthalene-1-sulfonato-κ2O:N] monohydrate] top
Crystal data top
[Ag(C10H8NO3S)(C18H15P)2]·H2OZ = 2
Mr = 872.66F000 = 896
Triclinic, P1Dx = 1.435 Mg m−3
Hall symbol: -P 1Mo Kα radiation
λ = 0.71073 Å
a = 10.017 (2) ÅCell parameters from Total reflections
b = 13.696 (3) Åθ = 1.3–27.5º
c = 16.792 (3) ŵ = 0.68 mm−1
α = 69.84 (3)ºT = 293 (2) K
β = 81.37 (3)ºBlock, colourless
γ = 69.09 (3)º0.29 × 0.24 × 0.19 mm
V = 2019.1 (9) Å3
Data collection top
Rigaku RAXIS-RAPID
diffractometer		8991 independent reflections
Radiation source: fine-focus sealed tube5525 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.006
T = 293(2) Kθmax = 27.5º
ω scanθmin = 1.3º
Absorption correction: multi-scan
Abscor (Higashi, 1995)		h = −13→12
Tmin = 0.823, Tmax = 0.886k = −16→17
9249 measured reflectionsl = −21→21
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.040H atoms treated by a mixture of
independent and constrained refinement
wR(F2) = 0.108  w = 1/[σ2(Fo2) + (0.0548P)2]
where P = (Fo2 + 2Fc2)/3
S = 0.91(Δ/σ)max = 0.001
8991 reflectionsΔρmax = 0.36 e Å−3
545 parametersΔρmin = −0.71 e Å−3
5 restraintsExtinction correction: none
Primary atom site location: structure-invariant direct methods
Crystal data top
[Ag(C10H8NO3S)(C18H15P)2]·H2Oγ = 69.09 (3)º
Mr = 872.66V = 2019.1 (9) Å3
Triclinic, P1Z = 2
a = 10.017 (2) ÅMo Kα
b = 13.696 (3) ŵ = 0.68 mm−1
c = 16.792 (3) ÅT = 293 (2) K
α = 69.84 (3)º0.29 × 0.24 × 0.19 mm
β = 81.37 (3)º
Data collection top
Rigaku RAXIS-RAPID
diffractometer		8991 independent reflections
Absorption correction: multi-scan
Abscor (Higashi, 1995)		5525 reflections with I > 2σ(I)
Tmin = 0.823, Tmax = 0.886Rint = 0.006
9249 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0405 restraints
wR(F2) = 0.108H atoms treated by a mixture of
independent and constrained refinement
S = 0.91Δρmax = 0.36 e Å−3
8991 reflectionsΔρmin = −0.71 e Å−3
545 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.45345 (3)0.40427 (2)0.73248 (2)0.03644 (10)
C10.7118 (4)0.6796 (3)0.6260 (2)0.0296 (8)
C20.6465 (4)0.7797 (3)0.6386 (3)0.0381 (9)
H20.54730.80910.63970.046*
C30.7281 (4)0.8386 (3)0.6499 (3)0.0472 (11)
H30.68270.90630.65890.057*
C40.8730 (4)0.7966 (3)0.6478 (3)0.0422 (10)
H40.92600.83560.65620.051*
C50.9447 (4)0.6948 (3)0.6331 (2)0.0296 (8)
C61.0960 (4)0.6543 (3)0.6255 (2)0.0341 (9)
H61.14860.69590.63000.041*
C71.1658 (4)0.5561 (3)0.6120 (2)0.0297 (8)
C81.0864 (4)0.4922 (3)0.6060 (2)0.0337 (9)
H81.13380.42370.59860.040*
C90.9410 (4)0.5301 (3)0.6111 (2)0.0327 (9)
H90.89070.48700.60640.039*
C100.8642 (4)0.6328 (3)0.6234 (2)0.0265 (8)
C110.7677 (4)0.1897 (3)0.6750 (2)0.0340 (9)
C120.8273 (4)0.2726 (3)0.6382 (3)0.0435 (10)
H120.78340.34070.64670.052*
C130.9527 (5)0.2544 (3)0.5885 (3)0.0504 (11)
H130.99240.31030.56410.060*
C141.0176 (4)0.1542 (3)0.5755 (3)0.0479 (11)
H141.10110.14220.54210.057*
C150.9590 (5)0.0715 (4)0.6118 (3)0.0571 (12)
H151.00310.00350.60310.069*
C160.8354 (5)0.0891 (3)0.6611 (3)0.0519 (12)
H160.79670.03260.68540.062*
C230.5068 (4)0.1420 (3)0.7161 (3)0.0358 (9)
C240.4707 (5)0.0553 (4)0.7733 (3)0.0553 (12)
H240.50020.02900.82890.066*
C250.3910 (5)0.0066 (4)0.7495 (3)0.0632 (14)
H250.3660−0.05130.78940.076*
C260.3486 (5)0.0425 (4)0.6680 (4)0.0645 (15)
H260.29560.00900.65210.077*
C270.3849 (6)0.1289 (5)0.6093 (4)0.084 (2)
H270.35820.15310.55320.101*
C280.4616 (6)0.1793 (4)0.6344 (3)0.0667 (16)
H280.48280.23940.59520.080*
C290.3320 (4)0.3793 (3)0.9567 (3)0.0381 (9)
C300.4519 (5)0.3871 (4)0.9811 (3)0.0657 (15)
H300.50610.42460.94080.079*
C310.4929 (7)0.3404 (5)1.0643 (4)0.0811 (18)
H310.57390.34701.07970.097*
C320.4151 (7)0.2843 (4)1.1243 (3)0.0765 (17)
H320.44250.25321.18050.092*
C330.2989 (6)0.2744 (4)1.1015 (3)0.0733 (16)
H330.24610.23581.14200.088*
C340.2573 (5)0.3214 (4)1.0178 (3)0.0562 (12)
H340.17690.31341.00290.067*
C350.1219 (4)0.4181 (3)0.8402 (2)0.0354 (9)
C360.1444 (5)0.3180 (3)0.8278 (3)0.0544 (12)
H360.23740.27180.82350.065*
C370.0321 (6)0.2860 (4)0.8221 (4)0.0694 (16)
H370.04930.21840.81450.083*
C38−0.1054 (6)0.3539 (4)0.8275 (3)0.0653 (14)
H38−0.18160.33190.82420.078*
C39−0.1309 (5)0.4541 (4)0.8378 (3)0.0601 (13)
H39−0.22430.50050.84070.072*
C40−0.0173 (4)0.4862 (3)0.8440 (3)0.0459 (10)
H40−0.03510.55440.85070.055*
C410.2170 (4)0.5942 (3)0.8473 (2)0.0347 (9)
C420.1378 (5)0.6255 (3)0.9147 (3)0.0503 (11)
H420.11260.57370.96120.060*
C430.0961 (5)0.7344 (4)0.9127 (4)0.0666 (14)
H430.04380.75540.95810.080*
C440.1319 (5)0.8109 (4)0.8436 (4)0.0623 (14)
H440.10160.88420.84180.075*
C450.2114 (5)0.7804 (3)0.7776 (3)0.0545 (12)
H450.23550.83300.73120.065*
C460.2569 (4)0.6714 (3)0.7790 (2)0.0387 (9)
H460.31350.65050.73460.046*
N11.3174 (3)0.5159 (3)0.6027 (2)0.0364 (8)
H1A1.346 (4)0.478 (3)0.569 (2)0.055*
H1B1.354 (4)0.568 (3)0.590 (3)0.055*
O10.6144 (3)0.5166 (2)0.68881 (18)0.0472 (8)
O20.4561 (3)0.6885 (2)0.60277 (19)0.0459 (7)
O30.6540 (3)0.5791 (2)0.53629 (19)0.0511 (8)
P10.60724 (10)0.21524 (7)0.74155 (7)0.0341 (2)
P20.27970 (10)0.45162 (8)0.84655 (6)0.0332 (2)
S10.60112 (9)0.61009 (7)0.61170 (6)0.0319 (2)
O1W0.2596 (5)0.9004 (4)0.5468 (4)0.1303 (19)
H1C0.331 (6)0.833 (3)0.556 (6)0.156*
H1D0.317 (8)0.946 (6)0.525 (6)0.156*
C170.6689 (4)0.1318 (3)0.8487 (3)0.0400 (10)
C180.8114 (8)0.0679 (8)0.8659 (5)0.060 (3)0.677 (15)
H180.88010.06460.82210.072*0.677 (15)
C190.8487 (10)0.0088 (10)0.9501 (6)0.081 (4)0.677 (15)
H190.9434−0.03450.96210.097*0.677 (15)
C200.7492 (7)0.0132 (5)1.0154 (3)0.0781 (17)
H200.7749−0.03001.07080.094*
C210.6107 (12)0.0823 (9)0.9983 (7)0.068 (3)0.677 (15)
H210.54320.08951.04230.081*0.677 (15)
C220.5737 (10)0.1405 (8)0.9153 (6)0.052 (2)0.677 (15)
H220.48030.18750.90410.062*0.677 (15)
C18'0.733 (3)0.0155 (15)0.8742 (13)0.085 (9)0.323 (15)
H18'0.7458−0.02130.83490.102*0.323 (15)
C19'0.778 (3)−0.0452 (15)0.9574 (12)0.084 (8)0.323 (15)
H19'0.8249−0.12090.97340.100*0.323 (15)
C21'0.677 (3)0.112 (2)0.9961 (14)0.080 (8)0.323 (15)
H21'0.65070.14671.03770.095*0.323 (15)
C22'0.634 (3)0.1745 (16)0.9095 (13)0.066 (6)0.323 (15)
H22'0.57930.24850.89730.079*0.323 (15)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.03352 (17)0.03216 (16)0.03996 (19)−0.00835 (11)0.00517 (13)−0.01209 (13)
C10.032 (2)0.033 (2)0.027 (2)−0.0151 (15)0.0019 (16)−0.0101 (16)
C20.032 (2)0.038 (2)0.048 (3)−0.0095 (16)0.0017 (18)−0.0198 (19)
C30.047 (3)0.037 (2)0.069 (3)−0.0148 (18)0.006 (2)−0.031 (2)
C40.045 (2)0.038 (2)0.057 (3)−0.0201 (18)0.000 (2)−0.025 (2)
C50.033 (2)0.0323 (19)0.028 (2)−0.0161 (15)−0.0009 (16)−0.0087 (16)
C60.037 (2)0.039 (2)0.035 (2)−0.0211 (16)−0.0038 (17)−0.0110 (17)
C70.0278 (19)0.038 (2)0.0248 (19)−0.0142 (15)−0.0039 (16)−0.0071 (16)
C80.032 (2)0.034 (2)0.041 (2)−0.0133 (15)−0.0031 (17)−0.0157 (17)
C90.033 (2)0.030 (2)0.042 (2)−0.0174 (16)−0.0005 (17)−0.0134 (17)
C100.0290 (19)0.0295 (18)0.0235 (19)−0.0138 (14)0.0000 (15)−0.0074 (15)
C110.032 (2)0.031 (2)0.039 (2)−0.0097 (15)0.0002 (17)−0.0126 (17)
C120.048 (3)0.032 (2)0.052 (3)−0.0156 (18)0.007 (2)−0.0160 (19)
C130.052 (3)0.047 (3)0.053 (3)−0.026 (2)0.011 (2)−0.013 (2)
C140.034 (2)0.054 (3)0.045 (3)−0.0109 (19)0.004 (2)−0.010 (2)
C150.048 (3)0.049 (3)0.076 (4)−0.012 (2)0.016 (2)−0.033 (2)
C160.049 (3)0.039 (2)0.073 (3)−0.0196 (19)0.022 (2)−0.028 (2)
C230.033 (2)0.030 (2)0.041 (2)−0.0095 (15)0.0016 (18)−0.0087 (17)
C240.075 (3)0.052 (3)0.044 (3)−0.034 (2)−0.005 (2)−0.006 (2)
C250.079 (4)0.050 (3)0.065 (3)−0.040 (3)−0.006 (3)−0.003 (2)
C260.059 (3)0.052 (3)0.088 (4)−0.028 (2)−0.021 (3)−0.010 (3)
C270.101 (5)0.095 (4)0.066 (4)−0.058 (4)−0.039 (3)0.005 (3)
C280.085 (4)0.065 (3)0.055 (3)−0.050 (3)−0.024 (3)0.009 (3)
C290.037 (2)0.036 (2)0.038 (2)−0.0059 (17)0.0013 (18)−0.0143 (18)
C300.066 (3)0.064 (3)0.066 (3)−0.030 (3)−0.024 (3)−0.001 (3)
C310.086 (4)0.082 (4)0.077 (4)−0.024 (3)−0.044 (4)−0.014 (3)
C320.098 (5)0.065 (4)0.043 (3)0.002 (3)−0.026 (3)−0.009 (3)
C330.074 (4)0.077 (4)0.043 (3)−0.012 (3)0.004 (3)−0.003 (3)
C340.041 (3)0.071 (3)0.046 (3)−0.017 (2)0.003 (2)−0.007 (2)
C350.036 (2)0.038 (2)0.032 (2)−0.0130 (17)−0.0010 (17)−0.0092 (17)
C360.050 (3)0.044 (3)0.072 (3)−0.013 (2)−0.009 (2)−0.021 (2)
C370.077 (4)0.054 (3)0.090 (4)−0.032 (3)−0.022 (3)−0.020 (3)
C380.061 (3)0.079 (4)0.068 (4)−0.043 (3)−0.013 (3)−0.012 (3)
C390.040 (3)0.078 (3)0.065 (3)−0.020 (2)−0.002 (2)−0.025 (3)
C400.039 (2)0.053 (3)0.048 (3)−0.019 (2)0.004 (2)−0.018 (2)
C410.030 (2)0.040 (2)0.037 (2)−0.0123 (16)0.0011 (17)−0.0151 (18)
C420.055 (3)0.047 (3)0.052 (3)−0.021 (2)0.021 (2)−0.024 (2)
C430.063 (3)0.065 (3)0.088 (4)−0.027 (3)0.031 (3)−0.052 (3)
C440.057 (3)0.042 (3)0.091 (4)−0.013 (2)0.004 (3)−0.032 (3)
C450.067 (3)0.042 (3)0.054 (3)−0.025 (2)−0.010 (3)−0.003 (2)
C460.043 (2)0.043 (2)0.032 (2)−0.0177 (18)−0.0018 (18)−0.0117 (18)
N10.0252 (17)0.047 (2)0.043 (2)−0.0135 (14)−0.0022 (15)−0.0201 (16)
O10.0428 (16)0.0426 (16)0.0540 (19)−0.0251 (13)−0.0090 (14)0.0022 (14)
O20.0262 (14)0.0445 (16)0.067 (2)−0.0110 (12)−0.0036 (14)−0.0175 (14)
O30.0448 (17)0.077 (2)0.0529 (19)−0.0266 (15)0.0033 (14)−0.0416 (16)
P10.0335 (5)0.0277 (5)0.0383 (6)−0.0081 (4)0.0033 (4)−0.0109 (4)
P20.0310 (5)0.0357 (5)0.0333 (6)−0.0111 (4)0.0036 (4)−0.0134 (4)
S10.0256 (5)0.0350 (5)0.0390 (6)−0.0137 (4)−0.0006 (4)−0.0127 (4)
O1W0.120 (4)0.109 (4)0.123 (5)0.026 (3)−0.021 (4)−0.048 (4)
C170.047 (3)0.030 (2)0.040 (2)−0.0078 (17)−0.001 (2)−0.0128 (18)
C180.043 (4)0.072 (6)0.050 (5)−0.002 (4)−0.006 (3)−0.016 (4)
C190.064 (6)0.085 (8)0.060 (6)0.011 (5)−0.023 (5)−0.011 (5)
C200.093 (5)0.071 (4)0.043 (3)0.001 (3)−0.016 (3)−0.010 (3)
C210.068 (7)0.071 (6)0.046 (5)−0.009 (5)0.000 (5)−0.012 (4)
C220.049 (5)0.047 (5)0.046 (5)−0.006 (4)0.008 (4)−0.012 (4)
C17'0.047 (3)0.030 (2)0.040 (2)−0.0078 (17)−0.001 (2)−0.0128 (18)
C18'0.12 (2)0.052 (11)0.075 (13)0.003 (11)−0.019 (12)−0.032 (10)
C19'0.116 (19)0.041 (11)0.061 (12)0.001 (10)−0.030 (12)0.007 (9)
C20'0.093 (5)0.071 (4)0.043 (3)0.001 (3)−0.016 (3)−0.010 (3)
C21'0.087 (19)0.098 (18)0.035 (10)0.010 (13)−0.017 (12)−0.034 (11)
C22'0.069 (15)0.039 (11)0.054 (11)0.018 (9)−0.008 (10)−0.007 (9)
Geometric parameters (Å, °) top
Ag1—P12.4598 (13)C33—H330.9300
Ag1—N1i2.460 (3)C34—H340.9300
Ag1—O12.478 (3)C35—C401.380 (5)
Ag1—P22.4837 (14)C35—C361.391 (5)
C1—C21.368 (5)C35—P21.823 (4)
C1—C101.430 (5)C36—C371.371 (6)
C1—S11.785 (3)C36—H360.9300
C2—C31.406 (5)C37—C381.370 (7)
C2—H20.9300C37—H370.9300
C3—C41.357 (5)C38—C391.371 (7)
C3—H30.9300C38—H380.9300
C4—C51.411 (5)C39—C401.387 (6)
C4—H40.9300C39—H390.9300
C5—C61.418 (5)C40—H400.9300
C5—C101.421 (5)C41—C421.385 (6)
C6—C71.357 (5)C41—C461.385 (5)
C6—H60.9300C41—P21.829 (4)
C7—C81.410 (5)C42—C431.387 (6)
C7—N11.423 (5)C42—H420.9300
C8—C91.361 (5)C43—C441.370 (7)
C8—H80.9300C43—H430.9300
C9—C101.412 (5)C44—C451.362 (7)
C9—H90.9300C44—H440.9300
C11—C121.384 (5)C45—C461.389 (6)
C11—C161.386 (5)C45—H450.9300
C11—P11.812 (4)C46—H460.9300
C12—C131.394 (6)N1—Ag1ii2.460 (3)
C12—H120.9300N1—H1A0.85 (4)
C13—C141.371 (6)N1—H1B0.87 (4)
C13—H130.9300O1—S11.457 (3)
C14—C151.375 (6)O2—S11.458 (3)
C14—H140.9300O3—S11.440 (3)
C15—C161.375 (6)P1—C171.827 (4)
C15—H150.9300O1W—H1C0.92 (6)
C16—H160.9300O1W—H1D0.94 (9)
C23—C241.370 (5)C17—C221.365 (10)
C23—C281.375 (6)C17—C22'1.29 (3)
C23—P11.829 (4)C17—C181.395 (8)
C24—C251.380 (6)C17—C18'1.42 (3)
C24—H240.9300C18—C191.396 (11)
C25—C261.362 (7)C18—H180.9300
C25—H250.9300C19—C201.370 (11)
C26—C271.378 (7)C19'—C201.40 (3)
C26—H260.9300C19—H190.9300
C27—C281.386 (6)C20—C211.377 (13)
C27—H270.9300C20—C21'1.24 (3)
C28—H280.9300C20—H200.9300
C29—C341.369 (6)C21—C221.377 (14)
C29—C301.375 (6)C21—H210.9300
C29—P21.826 (4)C22—H220.9300
C30—C311.378 (7)C18'—C19'1.40 (2)
C30—H300.9300C18'—H18'0.9300
C31—C321.368 (8)C19'—H19'0.9300
C31—H310.9300C21'—C22'1.45 (3)
C32—C331.343 (7)C21'—H21'0.9300
C32—H320.9300C22'—H22'0.9300
C33—C341.387 (7)
P1—Ag1—N1i117.56 (9)C29—C34—C33121.4 (5)
P1—Ag1—O1105.72 (7)C29—C34—H34119.3
N1i—Ag1—O190.32 (10)C33—C34—H34119.3
P1—Ag1—P2123.55 (5)C40—C35—C36118.0 (4)
N1i—Ag1—P2103.02 (9)C40—C35—P2124.7 (3)
O1—Ag1—P2111.83 (8)C36—C35—P2117.3 (3)
C2—C1—C10120.9 (3)C37—C36—C35121.3 (4)
C2—C1—S1118.0 (3)C37—C36—H36119.3
C10—C1—S1121.1 (3)C35—C36—H36119.3
C1—C2—C3120.6 (3)C38—C37—C36119.8 (5)
C1—C2—H2119.7C38—C37—H37120.1
C3—C2—H2119.7C36—C37—H37120.1
C4—C3—C2120.0 (4)C37—C38—C39120.2 (4)
C4—C3—H3120.0C37—C38—H38119.9
C2—C3—H3120.0C39—C38—H38119.9
C3—C4—C5121.2 (3)C38—C39—C40120.0 (5)
C3—C4—H4119.4C38—C39—H39120.0
C5—C4—H4119.4C40—C39—H39120.0
C4—C5—C6121.1 (3)C35—C40—C39120.7 (4)
C4—C5—C10119.6 (3)C35—C40—H40119.7
C6—C5—C10119.2 (3)C39—C40—H40119.7
C7—C6—C5121.5 (3)C42—C41—C46119.7 (4)
C7—C6—H6119.3C42—C41—P2122.3 (3)
C5—C6—H6119.3C46—C41—P2117.8 (3)
C6—C7—C8119.4 (3)C41—C42—C43119.8 (4)
C6—C7—N1121.8 (3)C41—C42—H42120.1
C8—C7—N1118.8 (3)C43—C42—H42120.1
C9—C8—C7120.4 (3)C44—C43—C42120.0 (5)
C9—C8—H8119.8C44—C43—H43120.0
C7—C8—H8119.8C42—C43—H43120.0
C8—C9—C10122.0 (3)C45—C44—C43120.5 (4)
C8—C9—H9119.0C45—C44—H44119.8
C10—C9—H9119.0C43—C44—H44119.8
C9—C10—C5117.4 (3)C44—C45—C46120.6 (4)
C9—C10—C1125.0 (3)C44—C45—H45119.7
C5—C10—C1117.6 (3)C46—C45—H45119.7
C12—C11—C16118.5 (4)C41—C46—C45119.3 (4)
C12—C11—P1119.0 (3)C41—C46—H46120.3
C16—C11—P1122.4 (3)C45—C46—H46120.3
C11—C12—C13120.3 (4)C7—N1—Ag1ii117.3 (2)
C11—C12—H12119.8C7—N1—H1A113 (3)
C13—C12—H12119.8Ag1ii—N1—H1A106 (3)
C14—C13—C12120.1 (4)C7—N1—H1B112 (3)
C14—C13—H13119.9Ag1ii—N1—H1B95 (3)
C12—C13—H13119.9H1A—N1—H1B113 (4)
C13—C14—C15119.8 (4)S1—O1—Ag1124.79 (15)
C13—C14—H14120.1C11—P1—C17103.95 (18)
C15—C14—H14120.1C11—P1—C23102.81 (18)
C14—C15—C16120.2 (4)C17—P1—C23104.17 (18)
C14—C15—H15119.9C11—P1—Ag1120.93 (12)
C16—C15—H15119.9C17—P1—Ag1112.91 (14)
C15—C16—C11121.0 (4)C23—P1—Ag1110.40 (12)
C15—C16—H16119.5C35—P2—C29103.94 (18)
C11—C16—H16119.5C35—P2—C41106.95 (17)
C24—C23—C28118.3 (4)C29—P2—C41100.11 (18)
C24—C23—P1124.6 (3)C35—P2—Ag1108.18 (14)
C28—C23—P1117.1 (3)C29—P2—Ag1118.33 (13)
C23—C24—C25120.9 (4)C41—P2—Ag1117.98 (13)
C23—C24—H24119.5O3—S1—O1113.63 (18)
C25—C24—H24119.5O3—S1—O2112.24 (18)
C26—C25—C24120.6 (4)O1—S1—O2111.77 (17)
C26—C25—H25119.7O3—S1—C1106.98 (17)
C24—C25—H25119.7O1—S1—C1105.24 (16)
C25—C26—C27119.5 (4)O2—S1—C1106.32 (16)
C25—C26—H26120.3H1C—O1W—H1D99 (4)
C27—C26—H26120.3C22—C17—C18118.6 (6)
C26—C27—C28119.5 (5)C22—C17—P1118.3 (5)
C26—C27—H27120.2C18—C17—P1122.8 (4)
C28—C27—H27120.2C17—C18—C19118.6 (7)
C23—C28—C27121.1 (4)C17—C18—H18120.7
C23—C28—H28119.4C19—C18—H18120.7
C27—C28—H28119.4C20—C19—C18121.5 (7)
C34—C29—C30117.4 (4)C20—C19—H19119.2
C34—C29—P2124.8 (3)C18—C19—H19119.2
C30—C29—P2117.8 (3)C19—C20—C21119.4 (7)
C29—C30—C31121.1 (5)C19—C20—H20120.3
C29—C30—H30119.5C21—C20—H20120.3
C31—C30—H30119.5C22—C21—C20119.1 (9)
C32—C31—C30120.3 (5)C22—C21—H21120.5
C32—C31—H31119.9C20—C21—H21120.5
C30—C31—H31119.9C17—C22—C21122.5 (8)
C33—C32—C31119.6 (5)C17—C22—H22118.7
C33—C32—H32120.2C21—C22—H22118.7
C31—C32—H32120.2C19'—C18'—H18'119.3
C32—C33—C34120.2 (5)C18'—C19'—H19'121.5
C32—C33—H33119.9C22'—C21'—H21'119.6
C34—C33—H33119.9C21'—C22'—H22'118.6
C10—C1—C2—C3−0.5 (6)C12—C11—P1—C23143.0 (3)
S1—C1—C2—C3−179.8 (3)C16—C11—P1—C23−38.6 (4)
C1—C2—C3—C40.5 (7)C12—C11—P1—Ag119.4 (4)
C2—C3—C4—C51.0 (7)C16—C11—P1—Ag1−162.2 (3)
C3—C4—C5—C6176.0 (4)C24—C23—P1—C11117.8 (4)
C3—C4—C5—C10−2.3 (6)C28—C23—P1—C11−64.2 (4)
C4—C5—C6—C7179.5 (4)C24—C23—P1—C179.6 (4)
C10—C5—C6—C7−2.1 (5)C28—C23—P1—C17−172.4 (4)
C5—C6—C7—C8−0.6 (5)C24—C23—P1—Ag1−111.9 (4)
C5—C6—C7—N1178.7 (3)C28—C23—P1—Ag166.1 (4)
C6—C7—C8—C92.1 (6)N1i—Ag1—P1—C1169.36 (17)
N1—C7—C8—C9−177.3 (3)O1—Ag1—P1—C11−29.46 (16)
C7—C8—C9—C10−0.7 (6)P2—Ag1—P1—C11−160.02 (14)
C8—C9—C10—C5−2.0 (5)N1i—Ag1—P1—C17−166.70 (17)
C8—C9—C10—C1177.4 (4)O1—Ag1—P1—C1794.48 (16)
C4—C5—C10—C9−178.3 (3)P2—Ag1—P1—C17−36.08 (15)
C6—C5—C10—C93.4 (5)N1i—Ag1—P1—C23−50.55 (17)
C4—C5—C10—C12.3 (5)O1—Ag1—P1—C23−149.38 (15)
C6—C5—C10—C1−176.1 (3)P2—Ag1—P1—C2380.07 (15)
C2—C1—C10—C9179.7 (4)C40—C35—P2—C2999.5 (4)
S1—C1—C10—C9−1.1 (5)C36—C35—P2—C29−82.6 (4)
C2—C1—C10—C5−0.9 (5)C40—C35—P2—C41−5.8 (4)
S1—C1—C10—C5178.4 (3)C36—C35—P2—C41172.0 (3)
C16—C11—C12—C13−0.1 (6)C40—C35—P2—Ag1−133.9 (3)
P1—C11—C12—C13178.4 (3)C36—C35—P2—Ag144.0 (3)
C11—C12—C13—C140.2 (7)C34—C29—P2—C35−4.1 (4)
C12—C13—C14—C15−0.2 (7)C30—C29—P2—C35178.7 (4)
C13—C14—C15—C160.1 (7)C34—C29—P2—C41106.4 (4)
C14—C15—C16—C110.0 (7)C30—C29—P2—C41−70.8 (4)
C12—C11—C16—C150.0 (7)C34—C29—P2—Ag1−124.0 (4)
P1—C11—C16—C15−178.4 (4)C30—C29—P2—Ag158.8 (4)
C28—C23—C24—C250.1 (7)C42—C41—P2—C3567.9 (4)
P1—C23—C24—C25178.1 (4)C46—C41—P2—C35−115.0 (3)
C23—C24—C25—C261.1 (8)C42—C41—P2—C29−40.2 (4)
C24—C25—C26—C27−0.5 (9)C46—C41—P2—C29136.9 (3)
C25—C26—C27—C28−1.2 (9)C42—C41—P2—Ag1−170.0 (3)
C24—C23—C28—C27−1.9 (8)C46—C41—P2—Ag17.1 (3)
P1—C23—C28—C27180.0 (5)P1—Ag1—P2—C35−78.12 (13)
C26—C27—C28—C232.5 (9)N1i—Ag1—P2—C3558.20 (15)
C34—C29—C30—C31−1.4 (7)O1—Ag1—P2—C35153.87 (14)
P2—C29—C30—C31176.0 (4)P1—Ag1—P2—C2939.60 (15)
C29—C30—C31—C320.5 (9)N1i—Ag1—P2—C29175.92 (16)
C30—C31—C32—C330.5 (9)O1—Ag1—P2—C29−88.41 (16)
C31—C32—C33—C34−0.5 (9)P1—Ag1—P2—C41160.41 (13)
C30—C29—C34—C331.3 (7)N1i—Ag1—P2—C41−63.27 (16)
P2—C29—C34—C33−175.9 (4)O1—Ag1—P2—C4132.40 (15)
C32—C33—C34—C29−0.4 (8)Ag1—O1—S1—O3−77.8 (2)
C40—C35—C36—C37−1.8 (7)Ag1—O1—S1—O250.5 (3)
P2—C35—C36—C37−179.8 (4)Ag1—O1—S1—C1165.49 (19)
C35—C36—C37—C380.7 (8)C2—C1—S1—O3129.4 (3)
C36—C37—C38—C390.7 (8)C10—C1—S1—O3−49.8 (3)
C37—C38—C39—C40−0.9 (8)C2—C1—S1—O1−109.4 (3)
C36—C35—C40—C391.6 (6)C10—C1—S1—O171.3 (3)
P2—C35—C40—C39179.4 (3)C2—C1—S1—O29.3 (4)
C38—C39—C40—C35−0.3 (7)C10—C1—S1—O2−169.9 (3)
C46—C41—C42—C431.4 (6)C11—P1—C17—C22174.5 (6)
P2—C41—C42—C43178.4 (3)C23—P1—C17—C22−78.1 (6)
C41—C42—C43—C440.8 (7)Ag1—P1—C17—C2241.7 (6)
C42—C43—C44—C45−1.7 (8)C11—P1—C17—C180.7 (6)
C43—C44—C45—C460.4 (7)C23—P1—C17—C18108.1 (6)
C42—C41—C46—C45−2.7 (6)Ag1—P1—C17—C18−132.1 (6)
P2—C41—C46—C45−179.9 (3)C22—C17—C18—C194.8 (12)
C44—C45—C46—C411.8 (6)P1—C17—C18—C19178.5 (7)
C6—C7—N1—Ag1ii89.1 (4)C17—C18—C19—C20−0.5 (16)
C8—C7—N1—Ag1ii−91.5 (4)C18—C19—C20—C21−3.8 (16)
P1—Ag1—O1—S1120.0 (2)C19—C20—C21—C223.7 (15)
N1i—Ag1—O1—S11.2 (2)C18—C17—C22—C21−4.9 (12)
P2—Ag1—O1—S1−103.0 (2)P1—C17—C22—C21−179.0 (7)
C12—C11—P1—C17−108.7 (3)C20—C21—C22—C170.6 (15)
C16—C11—P1—C1769.7 (4)
Symmetry codes: (i) x−1, y, z; (ii) x+1, y, z.
Hydrogen-bond geometry (Å, °) top
D—H···AD—HH···AD···AD—H···A
O1W—H1C···O20.92 (6)1.88 (3)2.789 (5)166 (8)
N1—H1B···O2ii0.87 (4)2.31 (2)3.140 (4)162 (4)
N1—H1A···O3iii0.85 (4)2.17 (2)2.975 (4)159 (4)
Symmetry codes: (ii) x+1, y, z; (iii) −x+2, −y+1, −z+1.
Table 1
Selected geometric parameters (Å, °) top
Ag1—P12.4598 (13)Ag1—O12.478 (3)
Ag1—N1i2.460 (3)Ag1—P22.4837 (14)
P1—Ag1—N1i117.56 (9)P1—Ag1—P2123.55 (5)
P1—Ag1—O1105.72 (7)N1i—Ag1—P2103.02 (9)
N1i—Ag1—O190.32 (10)O1—Ag1—P2111.83 (8)
Symmetry codes: (i) x−1, y, z.
Table 2
Hydrogen-bond geometry (Å, °) top
D—H···AD—HH···AD···AD—H···A
O1W—H1C···O20.92 (6)1.88 (3)2.789 (5)166 (8)
N1—H1B···O2ii0.87 (4)2.31 (2)3.140 (4)162 (4)
N1—H1A···O3iii0.85 (4)2.17 (2)2.975 (4)159 (4)
Symmetry codes: (ii) x+1, y, z; (iii) −x+2, −y+1, −z+1.
Acknowledgements top

We thank the Science Foundation for Young Teachers of Northeast Normal University (grant No. 20070314) for support.

references
References top

Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.

Rigaku Corporation (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.

Sheldrick, G. M. (1990). SHELXTL-Plus. Siemens Analytical X-Ray Instruments Inc., Madison, Wisconsin, USA.

Sheldrick, G. M. (1997). SHELXS97 and SHELXL97. University of Göttingen, Germany.

Wang, X.-Y., Ma, C.-H., Gao, Q.-Q., Lu, S.-Q. & Dong, X.-W. (2007). Acta Cryst. E63, m2361–?.