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Acta Cryst. (2007). E63, m2935-m2936 [ doi:10.1107/S1600536807055894 ]
-methoxo-bis[aquadimethoxonitrosylmolybdenum(II)]Abstract: The title complex, [Mo2(CH3O)6(NO)2(H2O)2], is a pseudocentrosymmetric dimer. The MoII centres are bridged by two methoxo groups and adopt distorted octahedral geometries. The crystal structure exhibits two intramolecular O-H
O contacts (O
O < 3.0 Å) between coordinated water molecules and methoxo groups. One H atom of each water molecule is disordered equally over two sites.
Online 9 November 2007
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