[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Buy article online]

[Contents scheme]

Acta Cryst. (2007). E63, m2935-m2936  [ doi:10.1107/S1600536807055894 ]

Di-[mu]-methoxo-bis[aquadimethoxonitrosylmolybdenum(II)]

J. Bucher, O. Blacque and H. Berke

Abstract: The title complex, [Mo2(CH3O)6(NO)2(H2O)2], is a pseudocentrosymmetric dimer. The MoII centres are bridged by two methoxo groups and adopt distorted octahedral geometries. The crystal structure exhibits two intramolecular O-H...O contacts (O...O < 3.0 Å) between coordinated water molecules and methoxo groups. One H atom of each water molecule is disordered equally over two sites.

Online 9 November 2007


Copyright © International Union of Crystallography
IUCr Webmaster