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Acta Cryst. (2007). E63, m2967 [ doi:10.1107/S1600536807053937 ]
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-1,1'-methylenediimidazole] hexafluoridophosphate]Abstract: The title compound, {[Ag(C7H8N4)]PF6}n, has a one-dimensional zigzag chain structure. The Ag+ cation and the PF6- anion reside on crystallographic inversion centres. The Ag+ cation is coordinated by the unsubstituted N atoms of two separate 1,1'-methylenediimidazole ligands. The closest Ag
Ag separation in the same cationic chain is 7.704 (2) Å and the dihedral angle between the two imidazole rings in the same ligand is 85.5 (1)°. A two-dimensional layer framework is formed by weak AgN interactions between adjacent chains, with an AgN distance of 3.472 (2) Å.
Online 9 November 2007
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