Acta Cryst. (2007). E63, m3105-m3106  [ doi:10.1107/S1600536807057212 ]

[-1,2-Bis(salicyloyl)hydrazine(4-)]bis[(ethylenediamine)zinc(II)] dimethylformamide disolvate dihydrate

Z.-Y. Wang and S.-X. Liu

Abstract: In the title compound, [Zn₂(C₁₄H₈N₂O₄)(C₂H₈N₂)₂]·2C₃H₇NO·2H₂O, the Zn₂ complex molecule lies on a crystallographic inversion centre. The two Zn atoms are bridged by two diazine N atoms of a 1,2-bis(salicyloyl)hydrazine(4-) ligand (bsh^4-); the inversion centre is located at the mid-point of the N-N bond. The coordination geometry of the Zn atom is distorted square-pyramidal. Each water molecule is linked with three surrounding binuclear complexes through four hydrogen bonds, resulting in a two-dimensional network.

Online 23 November 2007

Copyright © International Union of Crystallography
IUCr Webmaster