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Acta Cryst. (2007). E63, m2937  [ doi:10.1107/S1600536807055663 ]

[2'-(5-Chloro-2-oxidobenzylidene)benzenesulfonohydrazide-[kappa]2N,O][2'-(2-oxidobenzylidene)benzenesulfonohydrazide-[kappa]2N,O]copper(II)

H. M. Ali, J. Yusnita, M. R. Rizal and S. W. Ng

Abstract: The CuII atom (site symmetry \\overline{1}) in the title compound, [Cu(C13H10ClN2O3S)(C13H11N2O3S)], is N,O-chelated by the monoanionic ligands in a trans-CuN2O2 square-planar geometry. The 2'-(2-oxidobenzylidene)benzenesulfonohydrazide anion is disordered equallywith the chlorine-substituted 2'-(5-chloro-2-oxidobenzylidene)benzenesulfonohydrazide anion. An intermolecular N-H...O hydrogen bond helps to stabilize the crystal structure.

Online 9 November 2007


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