Acta Cryst. (2007). E63, m3010  [ doi:10.1107/S1600536807056838 ]

Di--chlorido-1:2²Cl,2:3²Cl-tetrachlorido-1Cl,2²Cl,3Cl-bis[N,N''-bis(2-furylmethylene)diethylenetriamine]-1³N,N',N'';3³N,N',N''-tricopper(II)

Q. Wang, D.-Q. Wang and Y.-Y. Sun

Abstract: The complete title trinuclear Cu^II complex, [Cu₃Cl₆(C₁₄H₁₆N₃O₂)₂], is generated by twofold symmetry with one Cu atom lying on the rotation axis. The central Cu atom adopts a distorted tetrahedral CuCl₄ geometry. The terminal Cu atom is five-coordinated in a distorted square-pyramidal coordination environment consisting of three N atoms of the ligand, one bridging Cl atom and one terminal Cl atom. Intermolecular C-HCl hydrogen bonds help to establish the packing.

Online 14 November 2007

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