Acta Cryst. (2007). E63, m3076-m3077  [ doi:10.1107/S1600536807058837 ]

Di--thiocyanato-bis[bis(tri-p-tolylphosphine)silver(I)] acetonitrile disolvate

G. J. S. Venter, R. Meijboom and A. Roodt

Abstract: In the centrosymmetric title compound, [Ag₂(NCS)₂(C₂₁H₂₁P)₄]·2CH₃CN, the Ag atom is coordinated by two phosphine ligands and two bridging thiocyanate ligands in a distorted tetrahedral configuration. The Ag-P bond distances are 2.4615 (7) and 2.5091 (7) Å, while the Ag-N and the Ag-S bond distances are 2.364 (2) and 2.3269 (18) Å, respectively. The crystal structure exhibits C-HS hydrogen bonds.

Online 21 November 2007

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