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Acta Cryst. (2007). E63, m2883  [ doi:10.1107/S1600536807052762 ]

Tetraaquabis[2-(3-benzoylphenyl)propanoato-[kappa]O]nickel(II) monohydrate

Z.-Y. Zhang, N. Yu, X.-X. Guo, J. Pu and J.-P. Sun

Abstract: The title complex, [Ni(C16H13O3)2(H2O)4]·H2O, is a transition metal complex of ketoprofen [2-(3-benzoylphenyl)propanoic acid], a well known non-steroidal anti-inflammatory drug. The asymmetric unit consists of half each of two complex molecules and one solvent water molecule. Both NiII atoms are located on crystallographic centres of inversion, each exhibiting an octahedral coordination geometry involving two carboxylate O atoms of different ketoprofenate ligands and four water molecules. A three-dimensional hydrogen-bonding framework is formed by O-H...O hydrogen-bonding interactions.

Online 7 November 2007


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