Acta Cryst. (2007). E63, m3013-m3014  [ doi:10.1107/S1600536807056371 ]

Poly[[bis[₂-1,3-bis(phenylsulfanyl)propane-²S:S']silver(I)] hexafluoridoantimonate diethyl ether hemisolvate]

M. O. Awaleh, A. Badia and F. Brisse

Abstract: The title compound, {[Ag(C₁₅H₁₆S₂)₂]SbF₆·0.5C₄H₁₀O}_n, was obtained from the self-assembly of AgSbF₆ and 1,3-bis(phenylsulfanyl)propane. Each Ag^I ion is coordinated by four S atoms from different ligands, forming a distorted tethrahedral geometry. Each ligand links adjacent Ag^I ions, forming an extended two-dimensional grid-like framework. SbF₆^- ions, which are incorporated into the cavities of the network, complete and stabilize the structure. One of the phenyl rings is disordered over two sites, the ratio of occupancies being 0.508 (4):0.492 (4).

Online 14 November 2007

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