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Acta Cryst. (2007). E63, i201  [ doi:10.1107/S160053680706000X ]

Caesium hexafluoridoiridate(IV)

A. I. Smolentsev, A. I. Gubanov, D. Y. Naumov and A. M. Danilenko

Abstract: Cs2[IrF6] possesses a framework structure constructed from Cs+ cations and [IrF6]2- complex anions. The cation is 12-coordinated by F atoms, forming a slightly distorted anticuboctahedron; the anion has the shape of an almost ideal octahedron. Cs, Ir and F atoms are located on special positions of 3m, \\overline{3}m and m symmetry, respectively.

Online 23 November 2007


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