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Acta Cryst. (2007). E63, m2893  [ doi:10.1107/S1600536807053792 ]

Di-[mu]-nitrato-[kappa]3O,O':O'';[kappa]3O:O',O''-bis[bis(3-nitrobenzohydrazide-[kappa]2N',O)cadmium(II)] dinitrate

S. Y. Chundak, L. Y. Lukachinec and M. Daszkiewicz

Abstract: The title compound, [Cd2(NO3)2(C7H7N3O3)2](NO3)2, contains centrosymmetric dimeric cations in which two nitrate anions each serve as a bidentate ligand to one Cd atom and a bridge to the other. The other anion in the asymmetric unit (half the formula unit) is uncoordinated. The ligands form an atypical seven-coordinated augmented trigonal prism around the CdII atom, with a displacement from the centre of the polyhedron in the direction of the uncoordinated nitrate anion. The crystal structure displays numerous N-H...O hydrogen bonds.

Online 7 November 2007


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