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Acta Cryst. (2007). E63, m2931  [ doi:10.1107/S1600536807054761 ]

[mu]-Glycine-[kappa]2O:O'-di-[mu]-sulfido-bis[(glycinato-[kappa]2N,O)oxidomolybdenum(V)]

Y. M. Li, Y. H. Li and C. P. Zhai

Abstract: In the title compound, [Mo2(C2H4NO2)2O2S2(C2H5NO2)], the two MoV atoms are bridged by two [mu]2-S atoms and one glycine ligand in an O:O'-bidentate mode. In addition, each MoV atom is bonded to one terminal oxygen ligand and chelated by one N,O-bidentate glycinate ligand, resulting in a distorted octahedral coordination. A complex hydrogen-bonding network is constructed by intermolecular N-H...O hydrogen bonds.

Online 9 November 2007


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