Acta Cryst. (2007). E63, m3041  [ doi:10.1107/S160053680705773X ]

Di--thocyanato-bis{2-bromo-4-chloro-6-[(2-methylaminoethylimino)methyl]phenolatocopper(II)}

P. Zhang

Abstract: The title compound, [Cu₂(C₁₀H₁₁BrClN₂O)₂(NCS)₂], is a centrosymmetric dithiocyanate-bridged binuclear copper(II) complex. The Cu^II atoms are pentacoordinated by the N,N',O-donor atoms of the Schiff base ligand 2-bromo-4-chloro-6-[(2-methylaminoethylimino)methyl]phenol (HBCP), and by one N and one S atom from two symmetry-related thiocyanate anions, so forming a slightly distorted square-pyramidal coordination configuration. The CuCu distance is 5.480 (2) Å.

Online 21 November 2007

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