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Acta Cryst. (2008). E64, m177  [ doi:10.1107/S1600536807065634 ]

N'-Ferrocenyl-2-hydroxybenzohydrazide

Y. Xu, C.-L. Chen, J. Zhou and M.-X. Li

Abstract: The title complex, [Fe(C5H5)(C13H11N2O3)], was prepared via self-assembly using ferrocenyl hydrazide and ethyl salicylate. The compound is potentially a tridentate ferrocene-based ligand. The conformation of the molecule allows the formation of an intramolecular N-H...O hydrogen bond involving the hydroxyl group. The CONHNHCO unit and the rings bonded to it are nearly coplanar. The crystal structure is stabilized by intermolecular O-H...O(carbonyl) and N-H...O(carbonyl) hydrogen bonds.

Online 12 December 2007


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