Acta Cryst. (2008). E64, m48  [ doi:10.1107/S160053680705742X ]

Tetrakis(N,N-diethylcarbamato)titanium(IV)

N. A. Straessler, M. T. Caudle and T. L. Groy

Abstract: The mononuclear title compound, [Ti(C₅H₁₀NO₂)₄], is a rare example of an eight-coordinate Ti^IV compound in which all donor atoms are O atoms. The coordination geometry around Ti^IV is pseudo-dodecahedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.

Online 6 December 2007

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