Acta Cryst. (2008). E64, m122  [ doi:10.1107/S1600536807065087 ]

(Piperazin-1-ium-N⁴)tris(thiocyanato-N)zinc(II)

X. He, H.-J. Liu and M.-X. Li

Abstract: Hydrothermal reaction of NaSCN, piperazine, Zn^II and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)₃(C₄H₁₁N₂)]. The Zn^II atom is four-coordinate with distorted tetrahedral geometry and lies in a mirror plane. N-HS hydrogen bonds assemble the molecules to form a three-dimensional framework.

Online 6 December 2007

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