Acta Cryst. (2008). E64, m203  [ doi:10.1107/S1600536807047514 ]

[(1-Azulenyl)methanethiolato-S](1,4,8,12-tetraazacyclopentadecane-⁴N)zinc(II) perchlorate

H. Görls, J. Notni and E. Anders

Abstract: In the title compound, [Zn(C₁₁H₂₆N₄)(C₁₁H₉S)]ClO₄, the Zn^II atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetraazacyclopentadecane aza-macrocycle molecule, and one S atom from an azulenylmethanethiolate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiolate group in an equatorial position. The Zn-N and Zn-S distances are in the usual ranges for this type of complex.

Online 18 December 2007

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