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Acta Cryst. (2008). E64, m96-m97 [ doi:10.1107/S1600536807064148 ]
-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvateAbstract: The title complex, [Ni2(C4H8N4O2)6](NO3)4·2CH4O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole ligands. The separation between the NiII atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octahedral coordination. Intermolecular N-H
O, N-H
N and O-H
O hydrogen bonds connect the ligands, solvent molecules and nitrate ions.
Online 6 December 2007
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