Acta Cryst. (2008). E64, m108  [ doi:10.1107/S1600536807063830 ]

Dichloridotriphenylantimony(V)-bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1)

L. Quan, H. Yin, J. Zhai and D. Wang

Abstract: The asymmetric unit of the title compound, [Sb(C₆H₅)₃Cl₂]·C₁₀H₁₆N₂S₄, comprises a bis(pyrrolidinylthiocarbamoyl) molecule and a dichlorotriphenylantimony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thiocarbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The molecules are connected by weak C-HS and C-HCl hydrogen-bonding interactions into two one-dimensional supramolecular chains.

Online 6 December 2007

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