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Acta Cryst. (2008). E64, m27 [ doi:10.1107/S1600536807061910 ]
![[kappa]](/logos/entities/kappa_rmgif.gif)
2S,S')bis(1,10-phenanthroline-2N,N')sodium(I)Abstract: The title compound, [Na(C4H7OS2)(C12H8N2)2], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal antiprism. A number of ![[pi]](/logos/entities/pi_rmgif.gif)
- stacking interactions involving the phen rings help to consolidate the crystal packing (centroid-centroid distances lie in the range 3.338-3.443 Å).
Online 6 December 2007
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