Acta Cryst. (2008). E64, m245  [ doi:10.1107/S1600536807067128 ]

Bis[1,2-bis(dimethylphosphino)ethane]dichloridonitrosyltungsten(0) chloride

N. Avramovic, O. Blacque, H. W. Schmalle and H. Berke

Abstract: In the crystal structure of the title compound, [WCl₂(NO)(C₆H₁₆P₂)₂]Cl, the seven-coordinated tungsten(II) center displays a distorted pentagonal-bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4.

Online 22 December 2007

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