Acta Cryst. (2008). E64, m87  [ doi:10.1107/S1600536807064288 ]

Di-tert-butylchlorido(pyrrolidine-1-dithiocarboxylato-²S,S')tin(IV)

F. Li, Y. Li, W. T. A. Harrison, W. Wang and Y. Feng

Abstract: The title compound, [Sn(C₄H₉)₂(C₅H₈NS₂)Cl], contains two molecules in the asymmetric unit, with similar conformations. In both molecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithiocarbamate ligand, with one Sn-S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.

Online 6 December 2007

Copyright © International Union of Crystallography
IUCr Webmaster