Acta Cryst. (2008). E64, m31  [ doi:10.1107/S1600536807062332 ]

Poly[[aqua(1-naphthylacetato)cadmium(II)]-₃-pyridin-3-olato]

C.-Y. Ma, W.-D. Song and D.-L. Xi

Abstract: In the title complex, [Cd(C₅H₄NO)(C₁₂H₉O₂)(H₂O)]_n, each Cd^II atom is coordinated by two carboxylate O atoms from one 1-naphthylacetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water molecule, and displays a distorted octahedral coordination geometry. The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthylacetate-Cd^II units parallel to the b axis, with a CdCd separation of 3.578 (2) Å. The chains are further self-assembled into a supramolecular network through intermolecular O-HO hydrogen-bonding interactions.

Online 6 December 2007

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