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Volume 64 
Part 2 
Page m363  
February 2008  

Received 22 November 2007
Accepted 26 December 2007
Online 16 January 2008

[bx2129sup1]
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© International Union of Crystallography 2008

Key indicators
Single-crystal X-ray study
T = 298 K
Mean [sigma](C-C) = 0.012 Å
R = 0.072
wR = 0.223
Data-to-parameter ratio = 16.0
Details
Open access

Poly[[{[mu]3-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}silver(I)] hexafluoridoantimonate]

Lian-Dong Liua*

aDepartment of Chemistry, Shandong Normal University, Jinan 250014, People's Republic of China
Correspondence e-mail: liandongliu1968@yahoo.com.cn

In the title compound, {[Ag(C30H20N6)][SbF6]}n, the Ag+ cation has a three-coordinate environment completed by three N atoms of the 1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane ligand. The Ag+ cation coordination geometry is best described as distorted T-shaped. The crystal structure forms a three-dimensional structural polymer.

Related literature

For a related structure, see: Wei et al. (2007[Wei, K.-J., Ni, J., Gao, J., Liu, Y.-Z. & Liu, Q.-L. (2007). Eur. J. Inorg. Chem. pp. 3868-3880.]).

[Scheme 1]

Experimental

Crystal data

  • [Ag(C30H20N6)][SbF6]

  • Mr = 808.14

  • Monoclinic, P 21 /c

  • a = 15.1652 (9) Å

  • b = 14.6022 (9) Å

  • c = 14.0711 (9) Å

  • [beta] = 94.2570 (10)°

  • V = 3107.4 (3) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.57 mm-1

  • T = 298 (2) K

  • 0.35 × 0.14 × 0.08 mm
Data collection

  • Bruker SMART APEX CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. Version 2.10. University of Göttingen, Germany.]) Tmin = 0.610, Tmax = 0.885

  • 15863 measured reflections

  • 5885 independent reflections

  • 4340 reflections with I > 2[sigma](I)

  • Rint = 0.032
Refinement

  • R[F2 > 2[sigma](F2)] = 0.071

  • wR(F2) = 0.223

  • S = 1.05

  • 5885 reflections

  • 367 parameters

  • 6 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 1.48 e Å-3

  • [Delta][rho]min = -0.94 e Å-3

Table 1
Selected geometric parameters (Å, °)

Ag1-N5 2.287 (6)
Ag1-N3 2.334 (5)
Ag1-N1i 2.354 (9)
N5-Ag1-N3 145.2 (2)
N5-Ag1-N1i 107.5 (3)
N3-Ag1-N1i 97.9 (3)
Symmetry code: (i) [-x+1, y-{\script{1\over 2}}, -z+{\script{3\over 2}}].

Data collection: SMART (Bruker, 1997[Bruker (1997). SMART (Version 5.6) and SAINT (Version 5.06A), Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 1997[Bruker (1997). SMART (Version 5.6) and SAINT (Version 5.06A), Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Bruker, 2001[Bruker (2001). SHELXTL. Version 6.12. Bruker AXS Inc., Madison, Wisconsin, USA.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BX2129 ).

References

Bruker (1997). SMART (Version 5.6) and SAINT (Version 5.06A), Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2001). SHELXTL. Version 6.12. Bruker AXS Inc., Madison, Wisconsin, USA.
Sheldrick, G. M. (1996). SADABS. Version 2.10. University of Göttingen, Germany.
Wei, K.-J., Ni, J., Gao, J., Liu, Y.-Z. & Liu, Q.-L. (2007). Eur. J. Inorg. Chem. pp. 3868-3880.  [CrossRef]

Acta Cryst (2008). E64, m363  [ doi:10.1107/S1600536807068432 ]