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Acta Cryst. (2008). E64, m300-m301 [ doi:10.1107/S1600536807068407 ]
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2N,N')(dimethylglyoxime-2N,N')cobalt(III)Abstract: In the title compound, [Co(C4H7N2O2)Cl2(C4H8N2O2)], the CoIII ion has a distorted octahedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethylglyoxime and dimethylglyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intramolecular O-H
O hydrogen bonds are observed between the dimethylglyoxime and dimethylglyoximate ligands. Molecules are linked into a chain running along the [101] direction by O-HO and C-HCl hydrogen bonds. The chains are cross-linked through intermolecular C-HCl hydrogen bonds.
Online 4 January 2008
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