Received 15 January 2008
Accepted 19 January 2008
Online 23 January 2008
|Single-crystal X-ray study|
|T = 293 K|
|Mean (C-C) = 0.013 Å|
|R = 0.063|
|wR = 0.139|
|Data-to-parameter ratio = 17.2|
aDepartment of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China, and bSchool of Heilongjiang Agricultural College of Vocational Technology, Jiamusi 154007, People's Republic of China
Correspondence e-mail: email@example.com
The asymmetric unit of the title mononuclear compound, [Ag(C6H5ClNO3S)(C18H15P)2], contains four independent molecules. In each of the molecules, the AgI cation is three-coordinated by two triphenylphosphine ligands, and one N atom from a 2-amino-5-chlorobenzenesulfonate anion. The molecules are linked into a one-dimensional supramolecular structure by N-HO hydrogen bonds.
For a related structure, see: Dong et al. (2007).
Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO; data reduction: PROCESS-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL-Plus (Sheldrick, 2008); software used to prepare material for publication: SHELXL97.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CI2554 ).
We thank the Science Foundation for Young Teachers of Northeast Normal University (grant No. 20070314) for support.
Dong, X.-W., Wu, F.-Y. & Li, Y.-J. (2007). Acta Cryst. E63, m2885.
Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.
Rigaku (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Acta Cryst (2008). E64, m395 [ doi:10.1107/S1600536808002031 ]