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Acta Cryst. (2008). E64, m348  [ doi:10.1107/S1600536808000044 ]

Aquabis(2-chloroacetato-[kappa]O)(1,10-phenanthroline-[kappa]2N,N')copper(II)

R. Yang, Y. Li, J. Sun, J. Li and C. Chu

Abstract: In the title complex, [Cu(C2H2ClO2)2(C12H8N2)(H2O)], the CuII ion is five-coordinated by two N atoms [Cu-N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu-O = 1.943 (2)-1.966 (2) Å] from two 2-chloroacetate ligands and one water molecule [Cu-O = 2.253 (2) Å] in a distorted square-pyramidal geometry. The crystal structure exhibits intermolecular O-H...O hydrogen bonds, short Cl...Cl contacts [3.334 (1) Å] and [pi]-[pi] interactions [centroid-centroid distance 3.621 (11) Å].


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