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Acta Cryst. (2008). E64, m275  [ doi:10.1107/S1600536807067761 ]

Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate

P. Liu and D.-S. Deng

Abstract: The triclinic unit cell of the title compound, [Ni(C3H4N2)2(H2O)4](C10H6O6S2), contains one centrosymmetric cation and one centrosymmetric anion. In the cation, the NiII ion is six-coordinated by two imidazole ligands [Ni-N = 2.0568 (14) Å] and four water molecules [both independent Ni-O distances are 2.098 (1) Å] in a distorted octahedral geometry. Intermolecular O-H...O and N-H...O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.

Online 4 January 2008


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