Acta Cryst. (2008). E64, o416  [ doi:10.1107/S160053680800024X ]

4-Aminophenylsulfur pentafluoride

E. L. Nava, A. Jesih and E. Goreshnik

Abstract: In the title compound, C₆H₆F₅NS, the environment of the S atom is roughly octahedral. The axial F-S bond appears slightly elongated with respect to the four equatorial F-S bonds. Equatorial F atoms are staggered with respect to the benzene ring. The N atom is displaced from the benzene plane by 0.154 (4) Å. The F-S-C-C torsion angles differ greatly from the values observed in the related structure of 4-acetamidophenylsulfur pentafluoride. The packing is stabilized by weak N-HF contacts.

Online 9 January 2008

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