[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2008). E64, o374  [ doi:10.1107/S1600536807062149 ]

4-(5-Bromo-2-hydroxybenzylideneamino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione

M. Wang, M. Cao, B. Hu, C. X. Cheng and X. G. Song

Abstract: In the title compound, C10H9BrN4OS, the triazole ring forms a dihedral angle of 72.05 (14)° with the benzene ring. The conformation of the molecule is stabilized by intramolecular O-H...·N hydrogen bonding. The crystal packing is determined by intermolecular N-H...S interactions, a short Br...S contact of 3.4464 (13) Å and [pi]-[pi] stacking of the triazole rings and of the benzene rings (centroid-centroid distances of 3.4109 and 3.569 Å, respectively).

Online 4 January 2008


Copyright © International Union of Crystallography
IUCr Webmaster