![[HTML version]](/e/graphics/htmlborder.gif)
![[PDF version]](/e/graphics/pdfborder.gif)
![[CIF]](/e/graphics/cifborder.gif)
![[3d view]](/e/graphics/3dviewborder.gif)
![[Structure Factors]](/e/graphics/structurefactorsborder.gif)
![[Supplementary Material]](/e/graphics/supplementarymaterialsborder.gif)
![[CIF check Report]](/e/graphics/checkcifborder.gif)
![[Issue contents]](/e/graphics/issuecontentsborder.gif)
![[Open access]](/e/graphics/free.gif)
![[Contents scheme]](hb2668contents.gif)
Acta Cryst. (2008). E64, m336-m337 [ doi:10.1107/S1600536808000378 ]
![[mu]](/logos/entities/mu_rmgif.gif)
2-aqua-tetraaquahexakis(4-naphthalene-2,6-dicarboxylato)tetraholmium(III)] 1.75-hydrate]Abstract: In the title compound, {[Ho4(C12H6O4)6(H2O)5]·1.75H2O}n, which is isostructural with its Tb3+- and Eu3+-containing analogues, there are four crystallographically independent Ho3+ centres, each exhibiting a highly distorted HoO8 bicapped trigonal-prismatic coordination environment. Adjacent polyhedra are interconnected via the carboxylate groups and one 2-bridging water molecule, forming one-dimensional chains propagating along [100]. The naphthalene-2,6-dicarboxylate ligands further interconnect these chains into a three-dimensional framework, which has zigzag channels housing the water molecules. Two naphthalene-2,6-dicarboxylate bridging ligands have their centroids located on crystallographic centres of inversion. One water O atom has a fixed site occupancy factor of 0.75.
Online 11 January 2008
Copyright © International Union of Crystallography
IUCr Webmaster