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Acta Cryst. (2008). E64, m266  [ doi:10.1107/S1600536807067323 ]

Diaquabis(9-oxo-4,5-diazafluoren-3-olato-[kappa]2N4,O3)cadmium(II)

Y.-H. Zhao, X. Yuan, W.-C. Qin, L.-X. Sheng and Y.-Z. Ding

Abstract: The title compound, [Cd(C11H5N2O2)2(H2O)2], is a mononuclear complex consisting of a CdII atom, two 3-hydroxy-4,5-diazafluoren-9-one ligands and two coordinated water molecules. The CdII atom, lying on a twofold axis, displays a distorted octahedral coordintion. Adjacent molecules are linked by O-H...O hydrogen bonds and [pi]-[pi] interactions [centroid-centroid distance = 3.84 (1) Å], leading to a one-dimensional chain. Weak C-H...O hydrogen bonds connect the chains into a two-dimensional supramolecular structure.

Online 4 January 2008


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