[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2008). E64, m307  [ doi:10.1107/S1600536808000226 ]

Bis{[mu]-2,2'-[1,1'-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-[kappa]5O,N,N',O':O}bis[chloridomanganese(III)]

V. S. Thampidas, T. Radhakrishnan and R. D. Pike

Abstract: The title compound, [Mn2(C18H18N2O2)2Cl2], was synthesized by the reaction between manganese(II) o-chlorobenzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The centrosymmetric dimer contains two Jahn-Teller-distorted manganese(III) ions, each in an octahedral geometry, connected through two phenoxy bridges from two ligands.

Online 9 January 2008


Copyright © International Union of Crystallography
IUCr Webmaster