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Acta Cryst. (2008). E64, m307 [ doi:10.1107/S1600536808000226 ]
-2,2'-[1,1'-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-
5O,N,N',O':O}bis[chloridomanganese(III)]Abstract: The title compound, [Mn2(C18H18N2O2)2Cl2], was synthesized by the reaction between manganese(II) o-chlorobenzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The centrosymmetric dimer contains two Jahn-Teller-distorted manganese(III) ions, each in an octahedral geometry, connected through two phenoxy bridges from two ligands.
Online 9 January 2008
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