Acta Cryst. (2008). E64, m290  [ doi:10.1107/S160053680706792X ]

trans-Carbonyl[dihydrobis(1,2,4-triazol-1-yl-N²)borato]hydridobis(triphenylphosphine-P)ruthenium(II) acetonitrile solvate

S. Huh

Abstract: In the crystal structure of the title compound, [Ru(C₄H₆BN₆)H(C₁₈H₁₅P)₂(CO)]·C₂H₃N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenylphosphine (PPh₃) ligands, one dihydrobis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one hydride atom within slightly distorted octahedra. The two P atoms of the PPh₃ ligands are trans positioned and the two N atoms of the chelating dihydrobis(1,2,4-triazol-1-yl)borate ligand occupy cis positions.

Online 4 January 2008

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