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Acta Cryst. (2008). E64, o419 [ doi:10.1107/S1600536808000408 ]
Abstract: The conformation of the N-H bond in the title compound (23DCPCA), C8H6Cl3NO, is syn to both the 2- and 3-chloro substituents in the aromatic ring, similar to the 2-chloro substituent in 2-chloro-N-(2-chlorophenyl)acetamide (2CPCA), the 2- and 3-chloro substituents in N-(2,3-dichlorophenyl)acetamide (23DCPA) and in 2,2-dichloro-N-(2,3-dichlorophenyl)acetamide (23DCPDCA). The bond parameters in 23DCPCA are similar to those in 2-chloro-N-(phenyl)acetamide, 2CPCA, 23DCPA, 23DCPDCA and other acetanilides. The molecules in 23DCPCA are linked into chains through N-H
O hydrogen bonding.
Online 11 January 2008
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